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网状结构5vol%TiBw/TA15复合材料抗腐蚀性能研究
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江苏大学 材料科学与工程学院,江苏 镇江 212013

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TB333

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国家自然科学基金(52305364);中国博士后科学基金(2023M741412);江苏省研究生科研与实践创新计划(SJCX23-2073)


Corrosion Resistance of 5vol%TiBw/TA15 Composite with Mesh Structure
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School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China

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    摘要:

    为了研究网状结构5vol%TiBw/TA15复合材料耐腐蚀性能,采用低能球磨加真空热压烧结技术制备5vol%TiBw/TA15复合材料。将纯TA15与5vol%TiBw/TA15复合材料进行电化学腐蚀试验,测量和比较2种材料在3.5wt% NaCl腐蚀 液环境中的开路电位、极化曲线和电化学阻抗谱。结果表明,相较纯TA15,5vol%网状结构增强TiBw/TA15复合材料具有低的自腐蚀电流密度(0.033 μA·cm-2)、更高极化电阻值(42 993 kΩ·cm2)和较少的腐蚀坑,显现出更优异的耐腐蚀性。这是由于TiBw增强体的存在,在电化学腐蚀过程中,相较于纯TA15,5vol%TiBw/TA15复合材料表面较快形成稳定的TiO2钝化膜。

    Abstract:

    The 5vol%TiBw/TA15 composite with mesh structure was prepared by low-energy ball milling in conjunction with vacuum hot pressing sintering technique, and its corrosion resistance was investigated. Pure TA15 and 5vol%TiBw/TA15 composite were subjected to electrochemical corrosion tests. The open circuit potential, polarization curves, and electrochemical impedance spectra of the two materials were measured and compared in 3.5wt% NaCl corrosion solution. The results show that compared with pure TA15, the composite reinforced by 5vol% TiBw with mesh structure has a lower self-corrosion current density (0.033 μA·cm-2), higher polarization resistance value (42 993 kΩ·cm2), and fewer corrosion pits, demonstrating superior corrosion resistance. This phenomenon is attributed to the presence of TiBw reinforcement, which accelerates the formation of a stable TiO2 passivation film on the surface of the 5vol%TiBw/TA15 composite compared to pure TA15 during the electrochemical corrosion process.

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冯养巨,王威,陆云彬,雷玉成.网状结构5vol%TiBw/TA15复合材料抗腐蚀性能研究[J].稀有金属材料与工程,2025,54(6):1588~1595.[Feng Yangju, Wang Wei, Lu Yunbing, Lei Yucheng. Corrosion Resistance of 5vol%TiBw/TA15 Composite with Mesh Structure[J]. Rare Metal Materials and Engineering,2025,54(6):1588~1595.]
DOI:10.12442/j. issn.1002-185X.20240056

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历史
  • 收稿日期:2024-01-30
  • 最后修改日期:2024-04-28
  • 录用日期:2024-05-08
  • 在线发布日期: 2025-06-10
  • 出版日期: 2025-06-09