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商用纯钛激光焊接接头及旋压成形材料在H2SO4/CuSO4电解溶液中的耐腐蚀及铜箔生成行为
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作者单位:

1.西安交通大学 金属材料强度国家重点实验室,陕西 西安 710049;2.西部钛业有限责任公司,陕西 西安 710201;3.西北工业大学 物理科学与技术学院,陕西 西安 710129;4.贵州航宇科技发展股份有限公司,贵州 贵阳 550081

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基金项目:

陕西省重点研发计划(2022GY-410)和西部钛业有限责任公司(WX2210)


Corrosion and Copper Foil Formation Behavior of Laser Welded and Spin Formed Commercially Pure Titanium in H2SO4/CuSO4 Electrolyte
Author:
Affiliation:

1.State Key Laboratory for Mechanical Behavior of Materials, Xi 'an Jiaotong University, Xi 'an 710049, China;2.Western Titanium Technolo-gies Co., Ltd, Xi'an 710201, China;3.School of Physical Science and Technology, Northwestern Polytechnical University, Xi'an 710129, China;4.Guizhou Aviation Technical Development Co., Ltd, Guiyang 550081, China

Fund Project:

Key Research and Development Program of Shaanxi Province (2022GY-410); Funding of Western Titanium Technologies Co., Ltd (WX2210)

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    摘要:

    在接头组织调控基础上,采用电化学阻抗谱、动电位极化及浸泡腐蚀等方法对比分析了两组样品的电化学腐蚀形貌及成膜后表面形貌差异,比较了激光接头样品和旋压成形样品在H2SO4/NaCl溶液和CuSO4还原电解质中的耐蚀性和成箔能力。结果表明,在H2SO4和NaCl溶液中,激光接头样品和旋压成形样品表现出优异的钝化能力和耐腐蚀性。两种样品在含Cl-的强酸性溶液中腐蚀形貌均匀,耐蚀性相似。同时,激光接头的铜箔形成能力与旋压成形材料相似,两种样品上均生成了表面质量较高,性能差异较小的完整铜箔。

    Abstract:

    Based on the regulation of joint microstructure, electrochemical impedance spectroscopy, kinetic potential polarization and immersion corrosion were used to comparatively analyze the differences in the electrochemical corrosion morphology and post-foil formation surface morphology of laser beam weld (LBW) sample and spin formed sample, and to compare the corrosion resistance and Cu foil-forming ability of two samples in H2SO4/NaCl solution and CuSO4 reducing electrolyte. Results show that in H2SO4 and NaCl solutions, LBW sample and spin formed sample exhibit excellent passivation ability and corrosion resistance. Both samples show uniform corrosion morphologies and similar corrosion resistance in the strong acidic solution containing Cl-. Meanwhile, the Cu foil formation ability of the welded joint is similar to that of the spin formed sample, and both samples obtain intact Cu foils with high-quality surfaces and small differences in properties.

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任利娜,宋燕飞,齐亮,杨健,雷晓维,杨家典,张建勋.商用纯钛激光焊接接头及旋压成形材料在H2SO4/CuSO4电解溶液中的耐腐蚀及铜箔生成行为[J].稀有金属材料与工程,2025,54(6):1467~1477.[Renlina, Songyanfei, Qiliang, Yang Jian, Leixiaowei, Yangjiadian, Zhangjianxun. Corrosion and Copper Foil Formation Behavior of Laser Welded and Spin Formed Commercially Pure Titanium in H2SO4/CuSO4 Electrolyte[J]. Rare Metal Materials and Engineering,2025,54(6):1467~1477.]
DOI:10.12442/j. issn.1002-185X.20240793

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历史
  • 收稿日期:2024-12-06
  • 最后修改日期:2025-01-10
  • 录用日期:2025-01-21
  • 在线发布日期: 2025-06-10
  • 出版日期: 2025-06-09