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钛在H2O2溶液中的腐蚀特性研究
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TG146.23

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Corrosion Behavior of Titanium in Hydrogen Peroxide Solutions
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    摘要:

    通过分光光度计测定腐蚀后溶液中钛离子浓度的方法,研究了钛在H2O2溶液中的腐蚀特性,以及不同pH值条件下,K^+,Ca^2+,Na^+,Mg^2+,Cl^-,HPO4^2-,H2PO4^-等添加离子对钛腐蚀的影响。结果表明:Ca^2+对钛腐蚀具有最强的抑制性,而HPO4^2-则具有最强的促进作用。分析认为:Ca^2+通过吸附到钛表面形成CaTiO3或者CaO2来抑制钛的腐蚀:而HPO4^2-则是吸附到钛表面来增加表面氧化膜的缺陷,从而促进钛的腐蚀。

    Abstract:

    The corrosion behavior of titanium in hydrogen peroxide solutions was studied by measuring the titanium ions concentration using spectrophotometer.The influence of additives(K+,Ca2+,Na+,Mg2+,Cl-,HPO42-,H2PO4-)on the corrosion behavior of titanium was discussed under different pH conditions.The results indicated that Ca2+ exhibited the highest inhibition to the titanium corrosion in hydrogen peroxide solutions.However,HPO42-behaved as an accelerator to the corrosion.It was considered that the Ca2+ inhibited the titanium corrosion probably by absorbed on the titanium surface to form a thin film of CaTiO3 or CaO2.The HPO42-accelerated the titanium corrosion,however,probably by increasing the defects of surface oxide films after absorption on the titanium surface.

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谢雷 王小祥.钛在H2O2溶液中的腐蚀特性研究[J].稀有金属材料与工程,2006,35(8):1219~1222.[Xie Lei, Wang Xiaoxiang. Corrosion Behavior of Titanium in Hydrogen Peroxide Solutions[J]. Rare Metal Materials and Engineering,2006,35(8):1219~1222.]
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  • 收稿日期:2005-05-23
  • 最后修改日期:2005-09-28
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