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稀土Y对Co43Fe20Ta5.5B31.5合金的非晶形成能力及性能的影响
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甘肃省教育厅开放基金(0503-08)


Effect of the Rare Earth Element Y on Glass-Forming Ability and Properties of Co43Fe20Ta5.5B31.5 Alloy
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    摘要:

    采用单辊甩带和铜模吹铸法,制备了(Co43Fe20Ta5.5B31.5)100-xYx(x=0.5, 1, 1.5, 2, 2.5, 3)合金薄带及φ2 mm的圆棒。X射线衍射及差热扫描量热分析表明:当x=3时合金具有最大的玻璃形成能力,可以很容易地制备出φ2 mm的非晶圆棒。该成分合金的约化玻璃转变温度Trg=0.657,参数γ=0.436,在所研究的系列成分中是最大的,这说明Trg和γ能够很好地表征Co-Fe-Ta-B合金的玻璃形成能力。压缩试验和磁滞回线测试表明,Y的添加导致Co-Fe-Ta-B非晶合金的压缩断裂强度和软磁性能急剧下降。φ2 mm的(Co43Fe20Ta5.5B31.5)97Y3非晶圆棒的压缩断裂强度为1852 MPa,断裂应变为0.18%。与Co43Fe20Ta5.5B31.5非晶合金相比,(Co43Fe20Ta5.5B31.5)97Y3非晶合金的磁滞回线上存在约327×79.6 A/m的矫顽力,同时饱和磁感应强度也显著下降。

    Abstract:

    The (Co43Fe20Ta5.5B31.5)100-xYx(x=0.5, 1, 1.5, 2, 2.5, 3)amorphous ribbons and rods of 2 mm diameters were prepared by melt spinning and copper mold blow- casting method. The analysis of XRD and DSC test indicated that the rod amorphous of 2 mm diameter was easily prepared owing to the alloy (x=3) which the value of x is 3 with maximum glass forming ability. Because the value of the reduced glass transition temperature (Trg) and γ of (Co43Fe20Ta5.5B31.5)97Y3 alloy were 0.657 and 0.436 respectively, which were maximum in the series chemical composition investigated, the glass forming ability of Co-Fe-Ta-B alloy was assessed by Trg and γ.The results of compression test and hysteresis loops showed that the compressive fracture strength and soft magnetic property of the Co-Fe-Ta-B amorphous alloy decreased dramatically when Y was added. The compressive fracture strength and the fracture strain of (Co43Fe20Ta5.5B31.5)97Y3 amorphous rods of 2 mm diameter were 1852 MPa and 0.18%, respectively. Compared with Co43Fe20Ta5.5B31.5, the coercivity Hc was 327×79.6 A/m in the hysteresis loops of the (Co43Fe20Ta5.5B31.5)97Y3 amorphous alloy, at the same time, the saturation magnetic flux density decreased distinctly.

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袁子洲,张大鹏,陆 叶,包石磊,佟亚东.稀土Y对Co43Fe20Ta5.5B31.5合金的非晶形成能力及性能的影响[J].稀有金属材料与工程,2009,38(1):138~142.[Yuan Zizhou, Zhang Dapeng, Lu Ye, Bao Shilei, Tong Yadong. Effect of the Rare Earth Element Y on Glass-Forming Ability and Properties of Co43Fe20Ta5.5B31.5 Alloy[J]. Rare Metal Materials and Engineering,2009,38(1):138~142.]
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  • 收稿日期:2008-01-19
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