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晶化对Co43Fe20Ta5.5B31.5非晶合金磁性能的影响
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甘肃省教育厅开放基金(0503-08);兰州理工大学优秀中青年基金


Effect of Crystallization on Magnetic Properties of Co43Fe20Ta5.5B31.5 Amorphous Alloy
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    摘要:

    采用单辊甩带法制备了Co43Fe20Ta5.5B31.5非晶合金薄带,利用差热分析、X-射线衍射以及振动样品磁强计研究了等温晶化和非等温晶化条件下晶化对显微组织和磁性能的影响。结果表明,等温晶化时,饱和磁感应强度Ms和矫顽力Hc都随晶化体积分数α的增加而增加。经过928 K保温55 min的晶化处理以后,合金的Ms值由制备态的37.2增加到58.4 A·m2/kg,与此同时矫顽力也由制备态的1.25×79.6 A/m增加到634.45×79.6 A/m。当只有(Co, Fe)21Ta2B6相析出时,Hc和

    Abstract:

    The Co43Fe20Ta5.5B31.5 amorphous ribbons were prepared by melt spinning. The effects of the crystallization under isothermal and non-isothermal conditions on microstructure and magnetic properties were investigated using X-ray diffraction (XRD), differential thermal analyzer (DTA), and vibrating samples magnetometer (VSM). It is found that the saturation magnetization Ms and the coercivity Hc increase with increasing of the crystallized volume fraction α under the condition of isothermal annealing. The Hc value of the alloy changes from 1.25×79.6 A/m for as-cast sample to 634.45×79.6 A/m for sample annealed at 928 K for 55 min, and at the same time the Ms value changes from 37.2 to 58.4 (A·m2)·kg-1. In the initial crystallization stage, the primary crystallization product is (Co, Fe)21Ta2B6 crystal, and the values of Hc and Ms increases gradually with increasing of α. Along with the development of crystallization, the values of Hc and Ms increase sharply when (Co, Fe)B and (Co, Fe)3B2 crystals precipitate. Under the non-isothermal crystallization conditions, the value of Ms increases monotonously with increasing of the stopping temperature, but the increase amplitude is very small. The value of Hc varies substantially with increasing of the stopping temperature, and the varying is non-monotonous. Within the temperature range of the first crystallization peak, the value of Hc increases monotonously with increasing of the stopping temperature. When the stopping temperature is higher then that of ending of the second crystallization peak, the value of Hc decreases drastically. When the stopping temperature increases from 968 to1153 K, the values of Ms and Hc increase from 61.74 to 67.7 A·m2/kg and from 267.6×79.6 to 416.2×79.6A/m, respectively. The Hc value decreases to 152.2×79.6 A/m when stopping temperature is up to 1273 K

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袁子洲,包石磊,佟亚东,姚 林.晶化对Co43Fe20Ta5.5B31.5非晶合金磁性能的影响[J].稀有金属材料与工程,2009,38(5):851~856.[Yuan Zizhou, Bao Shilei, Tong Yadong, Yao Lin. Effect of Crystallization on Magnetic Properties of Co43Fe20Ta5.5B31.5 Amorphous Alloy[J]. Rare Metal Materials and Engineering,2009,38(5):851~856.]
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  • 收稿日期:2008-05-19
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