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金属多孔球形银粉的制备
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Fabrication of Sphericity Nanoporous Metal Silver Powders
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    摘要:

    采用化学还原沉积法,以水合联氨为还原剂,在分散剂和自制的有机混和溶剂的保护下,控制溶液中银离子浓度为10~40 g.L-1,分散剂的加入量1.5~3 g.L-1,有机混合制剂60 g.L-1,还原反应在瞬间完成,还原出粒度为纳米级的银颗粒,在可控的条件下纳米颗粒聚集为多孔团粒银粉,快速从溶液中沉淀分离。采用扫描电镜检测,多孔团粒球体的粒度为40~80 μm; 采用比表面积及孔隙度检测仪测试比表面积可以达到16 m2/g以上,其孔道具有很高的通透性,不同于常规的超细银粉

    Abstract:

    The fabrication method of sphericity nanoporous metal silver powders by nanosilver powders is described in the present paper. In this technique, a chemical deoxidize deposited way is used by taking N2H4.H2O as deoxidizer, the nanosilver powders are prepared by deoxidized silver ions which are protected by the dispersant and the home-made organic mixed solution. The silver ions concentration, the dispersant adding amount, and the organic mixed preparation are 10~40 g/L, 1.5~3 g/L, and 60 g/L, respectively, in the solution, then the reduction reaction is finished instantly with a nanosilver granularity of 10~20 nm. The nanosilver powders are conglomerated to sphericity nanoporous silver powders under controllable conditions, fast separated from the solution by deposited. The morphology was studied using a JEOL JSM-6400 FESEM, the results show that the sphericity nanoporous silver powders granularity is 40 ~80 μm. The specific surface area of the nanoporous silver powders is more than 16 m2/g measured using a Micromeritics ASAP 2020, and its pore channel has a very high penetration, different from the traditional microminiature silver powders.

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张 健,李广忠,李 程,张文彦,奚正平.金属多孔球形银粉的制备[J].稀有金属材料与工程,2009,38(7):1150~1153.[Zhan Jian, Li Guangzhong, Li Cheng, Zhang Wenyan, Xi Zhengping. Fabrication of Sphericity Nanoporous Metal Silver Powders[J]. Rare Metal Materials and Engineering,2009,38(7):1150~1153.]
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  • 收稿日期:2008-12-08
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