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Fe41Co7Cr15Mo14C15B6Y2块体非晶合金在HCl溶液中的腐蚀行为
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Corrosion Behaviors of Bulk Amorphous Fe41Co7Cr15Mo14C15B6Y2
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    摘要:

    采用电化学极化曲线和电化学阻抗(EIS)测试方法研究Fe41Co7Cr15Mo14C15B6Y2块体非晶合金在0.5,1,2以及4 mol/L HCl溶液中的腐蚀行为,并比较了1 mol/L HCl 溶液中非晶合金和不锈钢的腐蚀行为。极化曲线测试结果表明,Fe41Co7Cr15Mo14C15B6Y2块体非晶合金在各种浓度的HCl溶液中都具有很好的耐蚀性,阳极极化曲线表现出明显的钝化特征。随着HCl溶液浓度的增大,其耐蚀性能逐渐下降。在1 mol/L HCl溶液中,非晶合金的自腐蚀电位高于不锈钢,自腐蚀电流密度比不锈钢小1个数量级。EIS结果显示,在开路电位下,Fe41Co7Cr15Mo14C15B6Y2非晶合金和不锈钢的Nyquist图均由单一的容抗弧构成,但非晶合金的电化学转移电阻Rt比不锈钢的大2个数量级,这一结果与极化曲线结果一致,说明非晶合金在HCl溶液中的耐蚀性能优于不锈钢

    Abstract:

    Corrosion behaviors of bulk amorphous Fe41Co7Cr15Mo14C15B6Y2 alloy in 0.5, 1, 2, 4 mol/L HCl solutions were studied by potentiodynamic polarization experiments and electrochemical impedance spectroscopy (EIS). Moreover, the corrosion behaviors of amorphous alloy and stainless steel were compared in 1 mol/L HCl solution. The results of potentiodynamic polarization experiment show that the amorphous Fe41Co7Cr15Mo14C15B6Y2 alloy has excellent corrosion resistance in different concentration of HCl solutions and its anodic reaction has a passive character. With the concentration of the HCl solutions increasing, the corrosion resistance of the amorphous alloy decreases. The results of potentiodynamic polarization experiments in 1 mol/L HCl solution show that the corrosion potential of the amorphous alloy is higher and the corrosion current density is lower than those of stainless steel. EIS experimental results show that the Nyquist figures of amorphous alloy and stainless steel are both composed of one single semi-circle in the state of open circuit potential. But the amorphous alloy has a higher charge transfer reaction resistance than the stainless steel. This result is accord with that of potentiodynamic polarization. The present results demonstrate that the corrosion resistance of bulk amorphous Fe41Co7Cr15Mo14C15B6Y2 alloy is much better than stainless steel.

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王 莉,范洪波,李 敬,郑 伟,晁月盛,沈 军. Fe41Co7Cr15Mo14C15B6Y2块体非晶合金在HCl溶液中的腐蚀行为[J].稀有金属材料与工程,2009,38(11):1992~1996.[Wang Li, Fan Hongbo, Li Jing, Zheng Wei, Chao Yuesheng, Shen Jun. Corrosion Behaviors of Bulk Amorphous Fe41Co7Cr15Mo14C15B6Y2[J]. Rare Metal Materials and Engineering,2009,38(11):1992~1996.]
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  • 收稿日期:2008-10-26
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