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辊速及晶化工艺对(Nd, Pr)13Fe80Nb1B6快淬薄带组织和矫顽力的影响
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国家重大基础研究前期专项(2004CCA04000);国家自然科学基金(50744014);浙江省科技计划重点项目(2008C21046); 浙江省自然科学基金(Y406389);江西省重要学科跨世纪学术和技术带头人培养计划资助项目(CA99110901); 宁波市科技攻关项目(2006B100054); 宁波大学王宽诚幸福基金


Effects of Wheel Velocity and Subsequent Crystallization on the Microstructures
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    摘要:

    用熔体快淬法制备(Nd,Pr)13Fe80Nb1B6快淬薄带并晶化处理,研究辊速和晶化条件对其组织和矫顽力的影响。结果表明,在10~20、25和35 m/s分别得到纳米晶、部分非晶和完全非晶薄带,且在18 m/s制备的薄带有较好的c轴各向异性。快淬态薄带的矫顽力随辊速(10~25 m/s)的增大而增加。非晶薄带晶化后由(Nd,Pr)2Fe14B相和富稀土相组成,且完全非晶薄带晶化后比部分非晶薄带晶化后的矫顽力要高,这是由于前者比后者具有更均匀的微结构造成的。非晶薄带晶化后矫顽力最大为1616 kA/m,高的矫顽力与添加Pr和Nb有关

    Abstract:

    (Nd,Pr)13Fe80Nb1B6 ribbons were melt-spun at 10~35 m/s and subsequently crystallized, the effect of wheel velocity and crystallization conditions on the microstructures and coercivities were studied. The XRD results indicate that the ribbons spun at 10~20 m/s consist of (Nd, Pr)2Fe14B nano-crystalline phase, while the ribbons spun at 25 and 35 m/s are partly and fully amorphous, respectively. In addition, the (004), (006) and (008) peaks of (Nd, Pr)2Fe14B are obvious on the ribbons spun at 18 m/s, suggesting the c-axis anisotropy. The coercivity of the ribbons prepared at 10~25 m/s increases with the increase of wheel velocity, with the maximum of 1216 kA/m at 25 m/s. After the ribbons spun at 25 m/s and 35 m/s are crystallized, the (Nd, Pr)2Fe14B phase and rich-rare earth phase are co-existed. And the coercivities of the ribbons spun at 35 m/s are much higher and with more homogeneous microstructures than those at 25 m/s. The maximum coercivity, 1616 kA/m, is obtained in the ribbons spun at 35 m/s after crystallizing at 973 K for 19 min due to the Pr and Nb addition. Because the Pr2Fe14B has a higher anisotropic coercive field than that of Nd2Fe14B, and the Nb element can inhibit the formation of α-Fe phase and refine the sizes of grains

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刘新才,郭鹏举,潘 晶,徐 峰,李 勇,崔 平.辊速及晶化工艺对(Nd, Pr)13Fe80Nb1B6快淬薄带组织和矫顽力的影响[J].稀有金属材料与工程,2009,38(11):2027~2031.[Liu Xincai, Guo Pengju, Pan Jing, Xu Feng, Li Yong, Cui Ping. Effects of Wheel Velocity and Subsequent Crystallization on the Microstructures[J]. Rare Metal Materials and Engineering,2009,38(11):2027~2031.]
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  • 收稿日期:2008-12-15
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