In the DMD-450 vacuum deposition system, the evaporation time and cycle times for Sr2CO3, Al2O3, Eu2O3, and Dy2O3 targets were changed by Alternate Electron Beam Evaporation method to prepare the blue-green film(GF) and the blue-purple film(PF). Variation of Al2O3/SrO molar ratio in the light-storing ceramic films with aluminate base will produce many different crystal phases which induce the various broadband 4f65d1→4f7 transitions of Eu2+ and the narrowband 5D0→7FJ transitions of Eu3+. Annealing conditions has great influence on the luminescent properties of the films, among which annealing temperature affects crystallization and the H2 proportion in annealing atmosphere has little influence on the film color but will affect its intensity.