Epitaxial DyBa2Cu3O7-x(DyBCO) superconductive thin film was fabricated via a F-free metal organic deposition (MOD) method on the (00l) single crystal substrate of LaAlO3. Because of the fluorine-free metal organic system, harmful gas by the normal TFA-MOD approach was avoided during the heat treatment. A high temperature treatment was introduced during the growth of DyBCO film and then the SEM observation shows denser microstructure and better texture of the film. X-ray diffraction pattern reveals the c-axis oriented grains. φ-scan also shows an excellent in-plane texture in the DyBCO film with a high temperature treatment. The DyBCO film fabricated by F-free MOD with a high temperature treatment has a superconductivity transition temperature of 92 K and a critical current density of 1.8 MA/cm2 at 77 K in self-field