+高级检索
HDDR法制备NdFeB永磁体的高矫顽力研究
DOI:
作者:
作者单位:

作者简介:

通讯作者:

中图分类号:

基金项目:

浙江省科学计划项目(2006C14014,2009C21010);浙江省优秀青年教师资助项目


Study on the Mechanism of the High Coercivity of NdFeB Magnets Prepared by HDDR Method
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    采用X射线衍射分析、扫描电镜和BH测试仪分别研究HDDR法制备的NdFeB永磁体微结构、晶粒表面形貌及其磁性能。结果表明,HDDR法制备的磁粉再经1080 ℃高温真空烧结所获得的NdFeB永磁体,主要由四方相Nd2Fe14B(P42/mnm)和少量的富稀土相构成,扫描电镜相片显示主相平均晶粒尺寸约为12.3 μm;采用Horta法计算得到样品(006)晶面的极密度因子约为3.5,表明该样品具有较高的c轴取向;不同温度下退磁曲线研究表明,室温下合金有较好的磁性能:磁能积 (BH)max=264 kJ/m3,剩磁Br=1.17 T,矫顽力达到Hcj=2038 kA/m;随温度的升高,磁性能各参数都单调下降,特别是矫顽力降低最为显著,从295 K升温到448 K过程中其值下降了1496 kA/m;Hc(T)/Ms(T)与H(T)/Ms(T)(Kronmüller-Plot)关系曲线研究表明,该合金的矫顽力机制为畴成核反转机制,其中微磁参数αk和Neff分别为1.39和1.75,是决定该合金高矫顽力的关键因素。

    Abstract:

    The microstructure, surface morphology, and magnetic properties of the sintered NdFeB permanent magnet prepared by the HDDR method were analyzed by X-ray diffraction, scanning electron microscopy and BH magnetic measurement. Microstructural studies show that NdFeB magnets which were firstly prepared by HDDR powder and then sintered at the high-temperature of 1080 oC consist of a large amount of the tetragonal phase Nd2Fe14B (P42/mnm) and trace amount of rare earth-rich phase. SEM images indicate that the average grain size of the Nd2Fe14B phase is about 12.3 μm. The density factor of (006) crystal face of Nd2Fe14B phase is estimated as about 3.5 using Horta formula, suggesting that the sample has a strong c-axis orientation. The demagnetic curves at different temperatures show that at room temperature this sample has well magnetic properties, i.e. (BH)max 264 kJ/m3, remanence Br about 1.17 T, and coercive Hcj 2038 kA/m. With the temperature increasing, magnetic properties of the samples are monotonicly reduced, especially for the coercivity which is reduced by 1496 kA/m from 295 to 448 K. The coercivity mechanism of the NdFeB magnets prepared by HDDR method was analyzed by studying the behavior of Hc(T)/Ms(T) versus (T)/Ms(T) (Kronmüller-plot). The results of Kronmüller-plot show that nucleation is the dominating mechanism for the magnetization reversal in these samples. Micromagnetic parameters αk of 1.39 and Neff of 1.75 are responsible for the high coercivity of magnetic alloys.

    参考文献
    相似文献
    引证文献
引用本文

张朋越,泮敏翔,朱津津,葛洪良,孙 浩,金一彪. HDDR法制备NdFeB永磁体的高矫顽力研究[J].稀有金属材料与工程,2011,40(6):1097~1011.[Zhang Pengyue, Pan Minxiang, Zhu Jinjin, Ge Hongliang, Sun Hao, Jin Yibiao. Study on the Mechanism of the High Coercivity of NdFeB Magnets Prepared by HDDR Method[J]. Rare Metal Materials and Engineering,2011,40(6):1097~1011.]
DOI:[doi]

复制
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2010-06-10
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期:
  • 出版日期: