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Effect of Pr on the Structure and Magnetic Properties of CoPt Alloys
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Effect of Pr on the Structure and Magnetic Properties of CoPt Alloys
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National Natural Science Foundations of China (50261002, 50661002)

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    摘要:

    对PrxCo50-xPt50 (x = 0, 0.2, 0.4, 0.6, 0.8, 1.0) 合金的显微结构和磁性能进行了研究。X射线衍射结果表明:经 1000 ℃均匀化后合金为单一的面心立方相(fcc),而经 675 ~ 750 ℃退火后合金由硬磁相(面心四方结构,fct)和软磁相组成。随着Pr含量增加,fct 的(111)衍射峰向高角度偏移,并且 c/a 增大导致有序度 S 减小。合金Pr0.4Co49.6Pt50 经 675 °C 退火 60 min 后,矫顽力和剩磁比达到最大值。PrxCo50-xPt50 (x = 0, 0.2, 0.4, 0.6, 0.8, 1.0) 经 675 °C 退火 60 min 的样品,矫顽力随着Pr含量的增加而单调减小,但剩磁比先增大后减小。

    Abstract:

    The effects of Pr on the microstructure and magnetic properties of PrxCo50-xPt50 alloys (x = 0, 0.2, 0.4, 0.6, 0.8, 1.0) were investigated. The XRD results indicate that all the alloys homogenized at 1000 °C contain only a single A1 (fcc) phase, while the alloys annealed at 675-750 °C consist of a hard-magnetic face-centered-tetragonal (fct) phase and a magnetically soft fcc phase. The (111) reflection belonging to the fct phase shifts to a higher angle and the c/a ratio increases as the Pr content increases, which leads to a decrease in the degree of ordering, S. Maximum values for the coercivity Hc and the remanence ratio mr are achieved in Pr0.4Co49.6Pt50 alloys annealed at 675 °C for 60 min. For the series of PrxCo50-xPt50 alloys annealed at 675 °C for 60 min, Hc decreases monotonically with increasing of Pr concentration, but mr is first enhanced and then weakened, showing a maximum value of 0.82 at x = 0.4 to 0.6.

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成 钢,顾正飞,何 维,邓 婷. Effect of Pr on the Structure and Magnetic Properties of CoPt Alloys[J].稀有金属材料与工程,2012,41(2):189~193.[Cheng Gang, Gu Zhengfei, He Wei, Deng Ting. Effect of Pr on the Structure and Magnetic Properties of CoPt Alloys[J]. Rare Metal Materials and Engineering,2012,41(2):189~193.]
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  • 收稿日期:2011-03-25
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