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添加Cr对Ti-Ni形状记忆合金相变和低温形变特性的影响
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陕西省自然科学基金 (2009JM6010);陕西省教育厅科研计划 (09JK375)


Effect of Adding Cr on Transformation and Low Temperature Deformation Characteristics in Ti-Ni Shape Memory Alloy
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    摘要:

    用示差扫描量热仪和拉伸试验研究了添加Cr对形变退火态Ti-Ni形状记忆合金相变和低温形变特性的影响。结果表明,添加微量Cr后,Ti-Ni合金的R、马氏体(M)相变温度θR和θM大幅度降低,M相变热滞ΔθM增加,应力-应变曲线的平台应力σM显著提高,超弹性(SE)改善,塑性变差。添加微量Cr后,Ti-Ni合金的低温SE特性大幅改善。室温下,Ti-50.8Ni合金呈现形状记忆效应(SME)+SE,而Ti-50.8Ni-0.3Cr合金则呈现SE。退火温度也显著影响Ti-Ni合金的低温形变特性。在10 ℃变形时,400~500 ℃退火态Ti-50.8Ni合金呈现SME,550~650 ℃退火态Ti-50.8Ni合金呈现SME+SE,而400~650 ℃退火态Ti-50.8Ni-0.3Cr合金则持续呈现SE。

    Abstract:

    The effects of adding Cr on the transformation and the low temperature deformation characteristics in the deformed plus annealed Ti-Ni shape memory alloy (SMA) were investigated by differential scanning calorimetry and tensile test. The results show that after adding trace Cr, the R and martensite (M) transformation temperatures θR and θM decrease a lot, the M transformation temperature hysteresis ΔθM increases, the platform-stress σM in the stress-strain curves increases significantly, and the superelasticity (SE) improves, and the ductility deteriorates in Ti-Ni SMA. After adding trace Cr, the low-temperature SE of Ti-Ni SMA also improves greatly. At room temperature, the Ti-50.8Ni SMA shows shape memory effect (SME) + SE, while the Ti-50.8Ni-0.3Cr SMA shows SE. The annealing temperature affects low temperature deformation characteristics of Ti-Ni SMA. When deformed at 10 oC, the 400-500 oC annealed Ti-50.8Ni SMA shows SME, the 550-650 oC annealed Ti-50.8Ni SMA shows SME + SE, while the 400-650 oC annealed Ti-50.8Ni-0.3Cr SMA shows SE continuously.

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杨 军,贺志荣,王 芳.添加Cr对Ti-Ni形状记忆合金相变和低温形变特性的影响[J].稀有金属材料与工程,2012,41(3):426~431.[Yang Jun, He Zhirong, Wang Fang. Effect of Adding Cr on Transformation and Low Temperature Deformation Characteristics in Ti-Ni Shape Memory Alloy[J]. Rare Metal Materials and Engineering,2012,41(3):426~431.]
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  • 收稿日期:2011-03-23
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