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稀土相RE-Sn表面Sn晶须的生长规律
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北京市教育委员会科技计划重点项目 (KZ200910005004);中国博士后科学基金 (20100480172)


Growth Law of Tin Whiskers on the Surface of the Oxidized RE-Sn Phases
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    摘要:

    将稀土相CeSn3、LaSn3、(La0.4Ce0.6)Sn3及ErSn3暴露于空气中,研究在时效处理过程中其表面Sn晶须的生长规律。结果表明:室温时效过程中,在稀土相的表面均出现了Sn晶须的生长现象,且稀土相LaSn3的表面倾向于形成包状和扭结状的Sn晶须,稀土相CeSn3和 (La0.4Ce0.6)Sn3的表面倾向于形成针状和扭结状的Sn晶须,而稀土相ErSn3的表面倾向于形成大尺寸的杆状和棒状Sn晶须。150 ℃时效过程中,稀土相CeSn3、LaSn3和 (La0.4Ce0.6)Sn3的表面没有出现Sn晶须的生长现象,而稀土相ErSn3的表面出现了大量的小尺寸线状Sn晶须。综上所述,稀土相的氧化倾向决定了其表面Sn晶须的生长规律

    Abstract:

    The growth law of tin whiskers on the surface of the oxidized CeSn3, LaSn3, (La0.4Ce0.6)Sn3 and ErSn3 precipitates was investigated during the aging. The results indicate that during aging at room temperature, rapid tin whisker growth was found on all of the oxidized RE-Sn surfaces, hillocks and kinked whiskers were easily formed on the oxidized LaSn3 surface, needle-like and kinked whiskers were easily formed on the oxidized CeSn3 and (La0.4Ce0.6)Sn3 surfaces, especially, large sized rod-like and stick-like whiskers were easily formed on the surface of the oxidized ErSn3 phase. During aging at 150 ℃, no whiskers were found on the surfaces of the oxidized CeSn3, LaSn3, (La0.4Ce0.6)Sn3 phases. However, a great number of thread-like whiskers were formed over the whole surface of the oxidized ErSn3 phase. In conclusion, the oxidation tendency of RE-Sn phases dominates the growth law of whisker on the oxidized RE-Sn surface

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郝 虎,郭 福,徐广臣,史耀武,宋永伦.稀土相RE-Sn表面Sn晶须的生长规律[J].稀有金属材料与工程,2012,41(8):1421~1425.[Hao Hu, Guo Fu, Xu Guangchen, Shi Yaowu, Song Yonglun. Growth Law of Tin Whiskers on the Surface of the Oxidized RE-Sn Phases[J]. Rare Metal Materials and Engineering,2012,41(8):1421~1425.]
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  • 收稿日期:2011-08-07
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