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钛合金熔模铸造二醋酸锆-氧化钇型壳的回溶及影响
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清华大学机械工程系,清华大学机械工程系,清华大学机械工程系

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国家自然科学基金项目(面上项目,重点项目,重大项目)


The mechanism and influence of re-dissolution in zirconium diacetate-yttria shell for titanium investment casting
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Department of Mechanical Engineering, Tsinghua University,Department of Mechanical Engineering, Tsinghua University,Department of Mechanical Engineering, Tsinghua University

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Fundamental Research Funds for the Central Universities (2012QNA26); National Natural Science Foundation of China (51006117, 51271099) and Special Financial Grant from the China Postdoctoral Science Foundation (2012T50524)

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    摘要:

    研究了二醋酸锆-氧化钇型壳(ZA-Y型壳)的回溶及其影响。使用重量法测定了型壳热水、蒸汽条件下的回溶率;使用电子万能试验机测定了型壳抗弯强度,并计算了裂纹指数随润湿时间的变化规律;利用光学显微镜(OM)观察了表面析出物的分布情况,用扫描电镜(SEM)结合能谱分析(EDS)研究了其形貌与成分,使用X射线荧光分析(XRF)方法测定了ZA-Y型壳的成分,并分析了表面析出物产生的原因。结果表明,型壳20 min内的回溶程度有限,最大吸水率为2.5%,回溶率为0.8%;强度下降26%,但裂纹指数下降至66%;表面析出物主要是由于偏钨酸铵的回溶,包含两种原因:泄压速度过快或后续干燥快而散热慢。

    Abstract:

    The re-dissolution of zirconium diacetate- yttria shell (ZA-Y shell) and its impact were studied. The re-dissolution rate under hot water and steamin miosture condition was measured by the balance. Three-point flexural strength was measured using the universal testing machine, and the fracture index was calculated. The distribution of the surface precipitates was observed by Ooptical microscope was used to observe the distribution of the surface precipitates, and its morphology and composition were tested using scanning electron microscopy (SEM) combined with energy spectrum analysis (EDS). Composition of the ZA-Y shell was measured by X-ray fluorescence (XRF) method. The reason of the precipitates was analysed. The results suggest the re-dissolution is limited. The maximum water penetration rate is 2.5% and the dissolution rate is 0.8% in 20 min. The strength reduces 26% and fracture index reduces to 66%. The surface precipitates are due to dissolution of ammonium metatungstate (AMT) and own two reasons: drastictoo high pressure release or fast drying condition with slow heat dissipation.

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郭馨,吕志刚,李培杰.钛合金熔模铸造二醋酸锆-氧化钇型壳的回溶及影响[J].稀有金属材料与工程,2016,45(2):303~308.[Guo Xin, Lu Zhigang, Li Peijie. The mechanism and influence of re-dissolution in zirconium diacetate-yttria shell for titanium investment casting[J]. Rare Metal Materials and Engineering,2016,45(2):303~308.]
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  • 收稿日期:2014-01-27
  • 最后修改日期:2014-02-25
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  • 在线发布日期: 2016-07-15
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