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多铁性陶瓷BiFeO3-PbTiO3-BaTiO3的介电、压电及其老化性能研究
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同济大学功能材料研究所

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TM221

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国家自然科学基金(项目编号50875181)


Dielectric, Piezoelectric and Aging Properties of Multiferroic Ceramics BiFeO3-BaTiO3-PbTiO3
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Functional Materials Research Laboratory of Tongji University,

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    摘要:

    采用高温固相法制备了钙钛矿结构的0.7BiFeO3-0.2PbTiO3-0.1BaTiO3陶瓷,研究了该陶瓷的介电性能、压电性能及其老化性能。结果表明,该陶瓷是一种非常有潜力的高温压电陶瓷,其介电常数和介电损耗分别为390和0.015,铁电居里温度Tc~600℃,压电常数d33~100pC/N,压电常数的时间和热稳定性好,热退极化温度Td~500℃。压电常数热退极化机理主要为内在的剩余极化老化,辅以低浓度氧空位等外在缺陷对畴壁的钉扎作用。

    Abstract:

    Multiferroic ceramics 0.7BiFeO3-0.2PbTiO3-0.1BaTiO3 (abbreviated as BF-BT-PT) was prepared by high temperature solid state method. The dielectric, piezoelectric properties and the aging behaviors were investigated. The results suggested that BF-PT-BT ceramics was a high potential lead-reduced high-temperature piezoceramics with excellent properties including the dielectric constant =390, =0.015, the piezoelectric coefficient of d33 ~100pC/N, the Curie temperature of Tc~600oC, good stability with the thermal depoling temperature of Td ~500oC. The primary thermal depoling mechanism was the decrease of remnant polarization, associated with the pinching effect on domain walls of low density oxygen vacancy defects.

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宁海霞.多铁性陶瓷BiFeO3-PbTiO3-BaTiO3的介电、压电及其老化性能研究[J].稀有金属材料与工程,2016,45(5):1249~1252.[Ning Haixia. Dielectric, Piezoelectric and Aging Properties of Multiferroic Ceramics BiFeO3-BaTiO3-PbTiO3[J]. Rare Metal Materials and Engineering,2016,45(5):1249~1252.]
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历史
  • 收稿日期:2014-05-14
  • 最后修改日期:2014-09-07
  • 录用日期:2014-09-28
  • 在线发布日期: 2016-06-02
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