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A Comparable Study on the Arrays of Aligned ZnO Nanowires and TiO2 Nanotubes for Applications of Dye- sensitized Solar Cells
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Priority Academic Program Development of Jiangsu Higher Education Institutions


A Comparable Study on the Arrays of Aligned ZnO Nanowires and TiO2 Nanotubes for Applications of Dye- sensitized Solar Cells
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    摘要:

    首先通过水热法在透明导电基底上合成出垂直有序的ZnO纳米线阵列,再对这些ZnO纳米线进行表面处理以得到TiO2纳米管阵列。随后,这些纳米线(管)阵列被用作光阳极组装染料敏化太阳电池(DSSC),以探索它们的光电化学性能。通过研究发现,用TiO2纳米管阵列组装而成的DSSC具有0.81%的太阳能转换效率,高出ZnO纳米线阵列组装而成的DSSC 3倍以上。另外,还运用一个简单的二极管模型对这些DSSC的伏安特性(J-V)曲线进行分析。最终发现,造成DSSC性能大幅度提高的原因在于其内部并联电阻的增加以及泄漏电流的下降。

    Abstract:

    Vertically aligned ZnO nanowire array (NWA) was synthesized on the transparent conductive substrates by a facile hydrothermal method. Then, TiO2 nanotube array (NTA) was obtained by a successive treatment of the ZnO NWA. Moreover, two dye-sensitized solar cells (DSSCs) were fabricated using these samples as the photoanodes in order to investigate their photoelectrochemical performance. It is found that TiO2 NTA demonstrates a power conversion efficiency of ~0.81 %, which is three times higher than ZnO NWA. The DSSC devices were used with a simple diode model to evaluate the current-voltage (J-V) curves. Finally, it was revealed that the cell performance improvement is attributed to an increased shuttle resistance and a suppressed leakage current.

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顾修全,强颖怀,赵宇龙. A Comparable Study on the Arrays of Aligned ZnO Nanowires and TiO2 Nanotubes for Applications of Dye- sensitized Solar Cells[J].稀有金属材料与工程,2014,43(6):1296~1299.[Gu Xiuquan, Qiang Yinghuai, Zhao Yulong. A Comparable Study on the Arrays of Aligned ZnO Nanowires and TiO2 Nanotubes for Applications of Dye- sensitized Solar Cells[J]. Rare Metal Materials and Engineering,2014,43(6):1296~1299.]
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  • 收稿日期:2013-06-25
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  • 在线发布日期: 2014-11-13
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