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堆内构件304L焊接件在除氧和氯离子环境中的应力腐蚀开裂研究
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中国原子能科学研究院

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TG

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国家重大专项资助项目2011ZX06004-009-0101,2011ZX06004-009-0402和核能开发资助项目HK?DG1001-20102301;国家科技攻关计划


The stress corrosion cracking behavior of reactor components welded 304L stainless steel in deoxygenized and chloride ions so
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China Institute of Atomic Energy(CIAE)

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    摘要:

    采用高温高压慢应变速率拉伸试验方法(SSRT),研究了在除氧环境下不同浓度氯离子对304L焊接件在模拟一回路高温高压硼锂水介质中氯致应力腐蚀开裂的影响。结果表明:当氯离子浓度为1mg/L时,其各项力学性能指标与惰性氮气空白样一致,表明在低浓度氯离子除氧条件下,304L焊接件没有应力腐蚀敏感性。随着氯离子含量(1mg/L-50mg/L)的增加,304L焊接件应力腐蚀敏感指数变化趋势是增加。断口侧面没有观察到明显的裂纹,氯离子浓度越低,断口缩颈现象越明显,表明主要是机械断裂。氯离子浓度较高时,棱角部分出现微裂纹源,可能与棱角部分应力更为集中相关。所有样品的断裂位置都在焊缝和热影响区,在焊缝和热影响区发生了巨大的形变,离断口越近,变形越严重。焊接部位是304L堆内构件中薄弱环节,应该成为应力腐蚀开裂和其他性能检测的重点部位。

    Abstract:

    Stress corrosion cracking(SCC) of reactor components welded 304L stainless steel in deoxygenized solution with different concentration chloride ions was studied using slow strain rate testing (SSRT), the basic water chemistry is simulated in pressure water reactor(PWR) primary loop, high temperature and high pressure water containing boric and lithium ion. Results shown the mechanical properties of welded 304L in 1mg/L chloride solution is equal those of welded 304L in inert nitrogen atmosphere, which implied welded 304L is immune to SCC in deoxygenized solution with low concentration chloride. The tendency of SCC susceptibility of welded 304L increased with increasing chloride ion concentration at range of 1mg/L to 50mg/L. There is not obvious crack on the side of fracture, the lower the chloride concentration, the more obvious the necking-down phenomenon, which implied the fracture mechanics is mainly mechanical fracture. There appeared microcracks source at angular parts, which is relative the stress gathering at these parts. The fracture position all lay in the weld and heat affected zone. There occurred huge deformation in the weld and heat affected zone, the near the fracture, the serious the deformation. The welded parts are weaknesses in the reactor components, which should be key monitoring sites for SCC susceptibility and other properties.

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彭德全.堆内构件304L焊接件在除氧和氯离子环境中的应力腐蚀开裂研究[J].稀有金属材料与工程,2016,45(7):1771~1776.[Peng DeQuan. The stress corrosion cracking behavior of reactor components welded 304L stainless steel in deoxygenized and chloride ions so[J]. Rare Metal Materials and Engineering,2016,45(7):1771~1776.]
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  • 收稿日期:2014-06-11
  • 最后修改日期:2014-06-19
  • 录用日期:2014-07-01
  • 在线发布日期: 2016-10-09
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