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Re2O3 (Re=Pr, Nd)掺杂SrTiO3陶瓷的结构与储能特性
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国家自然科学基金(51102121, 51262011);江西省自然科学基金(20114BAB216020);景德镇陶瓷学院博士科研启动项目(006000345)


Structure and Energy Storage Characteristics of Re2O3(Re=Pr, Nd)-Doped SrTiO3 Ceramics
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    摘要:

    采用固相法制备了稀土氧化物Re2O3 (Re=Pr, Nd)掺杂SrTiO3陶瓷,其化学式为[Re0.02Sr0.97(VSr)0.01]TiO3 (Re0.02Sr0.97TiO3: Re-STO, Re=Pr, Nd)。XRD分析结果表明,Re-STO陶瓷具有与纯SrTiO3(STO)陶瓷类似的单一立方钙钛矿结构。SEM分析发现Re-STO陶瓷的晶粒尺寸分布很不均匀,大晶粒在10 μm左右,而小晶粒只有1 μm左右,小晶粒填充在由大晶粒形成的晶界或三角晶界处。采用HP4294精密阻抗分析仪、JJC9906-A介电强度测试仪以及FMRL偏压测试系统测试了Re-STO陶瓷的介电性能,并评价了其储能特性。结果表明:在最佳烧成温度1350 ℃制备的Re-STO陶瓷在1 kHz下的相对介电常数(Pr-STO: εr=1860;Nd-STO: εr=1670)是纯STO陶瓷的(εr=300) 5倍以上,而介电损耗则保持在0.03 (1 kHz)以下;Re-STO陶瓷具有较高的击穿强度Eb>15 kV/mm;在本研究的偏压测试条件范围内,Re-STO陶瓷的εr变化均在±12%以内,其储能密度与偏压则符合二次抛物线关系。因此Re-STO陶瓷可近似认为是线性电介质,是中高压固态储能介质材料理想的候选体系。本研究还对Re-STO陶瓷的相结构、微观结构以及可能的缺陷结构与其介电性能、储能特性之间的关系进行了讨论

    Abstract:

    Rare earth oxides Re2O3 (Re=Pr, Nd) doped SrTiO3 ceramics with the formula of [Re0.02Sr0.97(VSr)0.01]TiO3 (Re0.02Sr0.97TiO3: Re-STO) were prepared by a solid state reaction method. The X-ray diffraction (XRD) results indicate that Re-STO ceramics have a single cubic perovskite structure which is similar to that of pure SrTiO3. Scanning electron microscopy (SEM) analysis shows inhomogeneous grain size distribution in Re-STO ceramics with big grains of about 10 μm and small ones of about 1 μm, and the small grains normally exist in grain boundaries and/or triangle grain boundaries among big grains. The dielectric properties of Re-STO ceramics were measured by HP4294 precision impedance analyzer, JJC9906-A breakdown strength testing instrument and FMRL bias voltage testing system, and the energy storage characteristics was evaluated. The results show that the relative dielectric constants of Re-STO ceramics (Pr-STO: εr=1860; Nd-STO: εr=1670), prepared at the optimized sintering temperature of 1350 oC, increase by more than 5 times than that of pure STO ceramics (εr=300 kHz), while the dielectric loss of Re-STO ceramics still remains lower than 0.03 (1 kHz). The breakdown strength Eb of Re-STO ceramics is higher than 15 kV/mm. Under the bias voltage testing conditions used in this study, the εr of Re-STO ceramics changes within ±12%, and the relationship between energy storage density and bias voltage is in good line with quadratic parabola function. Therefore, Re-STO ceramics can be treated as linear dielectrics, which should be very promising for medium/high voltage solid state energy storage applications. Meanwhile, the relationship between the phase structure, microstructure, possible defect structure and the dielectric properties, energy storage characteristics of Re-STO ceramics were also discussed.

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沈宗洋,胡其国,李月明,王竹梅,骆雯琴,洪 燕,谢志翔,洪 璐. Re2O3 (Re=Pr, Nd)掺杂SrTiO3陶瓷的结构与储能特性[J].稀有金属材料与工程,2014,43(7):1671~1675.[Shen Zongyang, Hu Qiguo, Li Yueming, Wang Zhumei, Luo Wenqin, Hong Yan, Xie Zhixiang, Hong Lu. Structure and Energy Storage Characteristics of Re2O3(Re=Pr, Nd)-Doped SrTiO3 Ceramics[J]. Rare Metal Materials and Engineering,2014,43(7):1671~1675.]
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  • 收稿日期:2013-07-28
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  • 在线发布日期: 2014-12-15
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