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高温合金GH 2984在750℃水蒸汽中的氧化行为研究
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西安热工研究院有限公司

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中图分类号:

TG132.3

基金项目:

国家自然科学基金项目(面上项目,重点项目,重大项目)


Oxidation Mechanism of GH 2984 Alloy in Pure Steam at 750℃
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National Natural Science Foundation of China

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    摘要:

    采用扫描电子显微镜、X射线衍射仪等研究了GH 2984合金在750℃纯水蒸汽中的氧化行为。结果表明:GH 2984合金表面形成单一的Cr2O3膜,其中固溶有少量TiO2。在氧化膜下方的金属基体尤其是其晶界处Ti、Al发生内氧化,分别形成TiO2和 Al2O3。合金的氧化动力学近似遵循抛物线规律。文章探讨了瘤状/刀片状Cr2O3的形成原因及GH 2984合金在750℃纯水蒸汽中的氧化机制。

    Abstract:

    Because of its superior high-temperature creep strength in combination with good workability and low cost compared to its Ni-Co-Cr based counterparts, GH 2984 alloy is evaluated to be a candidate material for applying as superheater/ reheater in 700℃ ultra-supercritical coal-fired power plants. At such high temperature (up to 700-760℃), the corrosion behavior of the alloy in steam is of great concern mainly due to the thickness of the oxide scales that are formed. In the present work, the oxidation behavior of GH 2984 alloy in pure steam at 750℃ has been investigated by using scanning electron microscope and X-ray diffractometer. The results show that a single Cr2O3 layer is formed with minor TiO2 solid soluted in it. Ti and Al are internally oxidized into TiO2 and Al2O3, respectively, preferentially along grain boundaries in the alloy underneath the Cr2O3 scale. The oxidation kinetic of the alloy observes a parabolic law. Investigation on the morphology evolution figures out that Cr2O3 blades formed initially which decreased in number and length and finally evolved into short rod-like ones with increasing oxidation time. The reason for the Cr2O3 nodules and blades formation and the oxidation mechanism of GH 2984 alloy in pure steam is discussed in detail.

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杨珍.高温合金GH 2984在750℃水蒸汽中的氧化行为研究[J].稀有金属材料与工程,2017,46(4):1013~1019.[yangzhen. Oxidation Mechanism of GH 2984 Alloy in Pure Steam at 750℃[J]. Rare Metal Materials and Engineering,2017,46(4):1013~1019.]
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历史
  • 收稿日期:2014-12-22
  • 最后修改日期:2015-03-04
  • 录用日期:2015-03-25
  • 在线发布日期: 2017-08-04
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