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高能球磨法制备MgB2材料的研究进展
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西北有色金属研究院,西部超导材料科技股份有限公司,西北有色金属研究院,西北有色金属研究院,西北有色金属研究院,西部超导材料科技股份有限公司,西北有色金属研究院,西北有色金属研究院,西部超导材料科技股份有限公司

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国家自然科学基金(51302226和51372207)项目,国家“973”计划(2011CBA00104) 和“863”计划(2014AA032701),陕西省自然(2014JQ6198)和陕西省创新团队(2013KCT-07)


Research Progress of MgB2 Superconducting MaterialsPrepared by High-energy Ball Milling
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Northwest Institute for Nonferrous Metal Research,Xi’an,Western Superconducting Technologies Co,Ltd,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an,Western Superconducting Technologies Co,Ltd,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an,Northwest Institute for Nonferrous Metal Research,Xi’an,Western Superconducting Technologies Co,Ltd,Xi’an

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    摘要:

    MgB2超导体临界温度为39 K,具有价格低廉和临界转变温度相对较高等优点,具有工程应用前景,然而其大尺度应用还依赖于超导性能的改善。经过系统的研究发现高能球磨和元素掺杂是提高MgB2磁场下Jc性能最有效的方法。本文介绍了采用高能球磨法制备MgB2的研究现状,采用高能球磨能有效细化晶粒,有利于提高超导芯丝的致密度,强化MgB2晶粒的连接性,同时晶粒细化形成的更多晶界能形成钉扎中心,进一步提高线/带材在高磁场下的临界电流密度。我们还介绍了通过分步反应法和高能球磨在常压条件下合成MgB2,高能球磨法可以减少MgB2长线中的孔洞并提高粉体密度。

    Abstract:

    Since the discovery of superconductivity at 39 K in MgB2, it has been considered as one of the most promising candidates for engineering applications due to its low material cost and relativity high critical transition temperature. However, the realization of large-scale application for MgB2 based superconducting technology essentially relies on the improvement of superconducting properties of MgB2. Some techniques have been developed to improve the critical current density, such as chemical doping, high-energy ball milling and various processing techniques. We introduce some research progress of MgB2 superconducting materials prepared by high-energy ball milling. The investigation showed high-energy ball milling is effective to obtain high density and fine grain size MgB2with high Jc performance. We also introduce that high Jc MgB2 was synthesized by two-step reaction method and high-energy ball milling. High-energy ball milling may be a good choice for reducing the void percentage and enhancing the average density in MgB2 long wires.

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杨芳,闫果,张平祥,王庆阳,熊晓梅,李少强,冯建情,李成山,冯勇.高能球磨法制备MgB2材料的研究进展[J].稀有金属材料与工程,2017,46(5):1452~1456.[Yang Fang, Yan Guo, Zhang Pingxiang, WangQingyang, Xiong Xiaomei, Li Shaoqiang, Feng Jianqing, Li Chengshan, Feng Yong. Research Progress of MgB2 Superconducting MaterialsPrepared by High-energy Ball Milling[J]. Rare Metal Materials and Engineering,2017,46(5):1452~1456.]
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历史
  • 收稿日期:2015-01-22
  • 最后修改日期:2015-03-03
  • 录用日期:2015-03-25
  • 在线发布日期: 2017-09-27
  • 出版日期: