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WO3纳米片的制备、表征及气敏性能研究
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大连海事大学环境科学与工程学院,大连海事大学环境科学与工程学院,大连海事大学环境科学与工程学院,大连海事大学环境科学与工程学院,大连海事大学环境科学与工程学院

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辽宁省教育厅科研计划项目(L2013203),辽宁省自然基金(2014025014)和中央高校基本科研业务费项目(3132015219)


Synthesis, characterization, and gas sensing properties of WO3 nanoplates
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School of Environment Science and Engineering,Dalian Maritime University,1 Linghai Road,School of Environment Science and Engineering,Dalian Maritime University,1 Linghai Road,School of Environment Science and Engineering,Dalian Maritime University,1 Linghai Road,School of Environment Science and Engineering,Dalian Maritime University,1 Linghai Road,School of Environment Science and Engineering,Dalian Maritime University,1 Linghai Road

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    摘要:

    论文采用水热法合成WO3纳米片,利用扫描电镜(SEM)和X射线衍射(XRD)对WO3纳米片的形貌特征和结构性能进行表征,并进一步系统地考察了利用WO3纳米片制备的传感器的气敏性能。实验结果表明,合成的WO3纳米片尺寸规则,边长在200-300 nm,厚度在50 nm左右,结晶性好。以WO3纳米片为材料制备的气体传感器的最佳工作温度为300 oC,在此工作温度下,WO3纳米片传感器对乙醇表现出超快的响应(2-4秒)和恢复时间(4-16 S)。与其他还原性气体如甲醇,苯、二氯甲烷和正己烷对比检测发现,WO3纳米片传感器对乙醇表现出高的灵敏度和选择性,表明WO3纳米片在乙醇检测气体传感器方面具有极大的应用潜力。

    Abstract:

    WO3 nanoplates are synthesized by a hydrothermal method. Morphology and structure of the WO3 nanoplates are analyzed by SEM and XRD. Gas sensing properties of the as-prepared WO3 sensor are investigated by a static gas-sensing system. The results show the WO3 nanoplates demonstrate good crystallinity with mean edge length of 200-300 nm and wall thickness of about 50 nm. The optimal operating temperature of the WO3 sensors is 300?C. At this operating temperature, the WO3 sensor exhibits ultra-fast response (2-4 s) and fast recovery time (4-16 s) for ethanol detection, and high selectivity to other gases such as methanol, benzene, dichloromethane and hexane, which indicates its excellent potential application as a gas sensor for ethanol detection.

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肖井坤,宋成文,董伟,李晨,尹妍妍. WO3纳米片的制备、表征及气敏性能研究[J].稀有金属材料与工程,2017,46(5):1241~1244.[Jingkun Xiao, Chengwen Song, Wei Dong, Chen Li, Yanyan Yin. Synthesis, characterization, and gas sensing properties of WO3 nanoplates[J]. Rare Metal Materials and Engineering,2017,46(5):1241~1244.]
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  • 收稿日期:2015-02-10
  • 最后修改日期:2015-06-12
  • 录用日期:2015-08-11
  • 在线发布日期: 2017-09-27
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