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高电导率Mg-Al-Sr耐热镁合金的研究
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国家自然科学基金(50725413);科技部合作项目 (2011BAE22B04);重庆市自然科学基金(CSTC2013JCYJC60001);重庆市自然科学基金(CSTC2013JJB50006)


Heat Resistant Mg-Al-Sr Alloys with High Electrical Conductivity
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    摘要:

    采用普通铸造法制备了Mg-3Al-xSr (x=0.1~0.9,质量分数,%)系列合金。利用金相显微镜、XRD、SEM、电导率测量仪和显微硬度仪等手段对该系列合金的金相组织、显微结构、电导率及维氏显微硬度等性能进行了测试。结果表明,在Mg-3Al合金中添加少量Sr元素 (<0.1%)会生成Al4Sr相,而继续增加Sr后 (>0.1%)合金中开始出现Mg-Al-Sr相 (τ相),Mg-Al-Sr铸态合金的电导率因此随着Sr含量的增加而不断提高;经高温热处理后 (400 ℃),热处理态Mg-Al-Sr合金的电导率均随着热处理时间的延长而不断增加,这主要是由τ相逐渐分解并转变为Al4Sr相引起的;添加少量的Sr (<0.1%)会降低Mg-3Al合金的显微硬度,而随着Sr元素的继续添加 (>0.1%),合金的显微硬度先增大后减小,并在Sr含量达到0.6%时达到峰值;此外,高温热处理会降低Mg-Al-Sr铸态合金的显微硬度。

    Abstract:

    Mg-3Al-xSr (x=0.1~0.9 wt%) alloys were prepared by a traditional cast method. Microstructures, electrical conductivities and micro-hardness of the present alloys in as-cast and as-heat treated states were studied by means of optical microscope, SEM, XRD, electrical conductivity meter and micro-hardness measuring instruments. The results show that Al4Sr phase is formed with little addition of Sr (<0.1 wt%). With increasing content of Sr, the electrical conductivity of as-cast Mg-Al-Sr alloys increases, and Mg-Al-Sr ternary phase (τ phase) is formed. After high temperature heat treatment at 400 oC, τ phase would decompose to Al4Sr phase, and the corresponding electrical conductivity of Mg-Al-Sr alloys increases with the heating time increasing. Vickers hardness of the as-cast alloy decreases slightly with a small amount of Sr addition (<0.1 wt%). With the increasing content of Sr (>0.1 wt%), the hardness of the alloys increases first, reaching the peak hardness at 0.6 wt% Sr and then decreases. Moreover, the high temperature treatment would decrease the corresponding hardness for as-cast alloys.

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潘虎成,潘复生,张 磊,彭 建,吴 璐,吕斌江,黄美娜,赵朝勇.高电导率Mg-Al-Sr耐热镁合金的研究[J].稀有金属材料与工程,2015,44(3):727~732.[Pan Hucheng, Pan Fusheng, Zhang Lei, Peng Jian, Wu Lu, Lü Binjiang, Huang Meina, Zhao Chaoyong. Heat Resistant Mg-Al-Sr Alloys with High Electrical Conductivity[J]. Rare Metal Materials and Engineering,2015,44(3):727~732.]
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  • 收稿日期:2014-03-18
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  • 在线发布日期: 2015-05-29
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