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采用低氟溶胶-凝胶法在725℃煅烧温度下制备YBCO超导薄膜的研究
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西安理工大学 材料物理与化学系,西安理工大学 材料物理与化学系,西安理工大学 材料物理与化学系,西安理工大学 现代分析测试中心,西北有色金属研究院

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国家自然科学基金项目(面上项目,重点项目,重大项目)


Preparation of YBa2Cu3O7-x Films at the Firing Temperature of 725 °C by a Low-Fluorine Sol-Gel Method
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Xi'an University of Technology,,,,

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The Project of Introducing Talents of Discipline to Universities (“111” Project, B08040); The International Cooperation Fund of the State Key Laboratory of Solidification Processing in NWPU

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    摘要:

    采用低氟溶胶-凝胶法在LaAlO3(100)基板上制备了YBa2Cu3O7-x (YBCO)薄膜,研究了725℃的煅烧过程中氧含量对最终所得到YBCO薄膜的临界电流密度Jc的影响。研究发现,煅烧过程中氧气含量在100-1700 ppm范围内时,所获得的YBCO薄膜均具有良好的双轴织构特征。然而,当氧气含量较小时,所获得的YBCO薄膜致密性差,Jc较低。随着氧气含量的增大,YBCO薄膜表面逐渐变得致密。当氧气含量增加到300ppm时,YBCO薄膜表面较致密,Jc值达到4.3MA/cm2。继续增大氧含量,薄膜表面出现富铜的第二相颗粒并逐渐增多,导致薄膜Jc降低。

    Abstract:

    In this paper, the YBa2Cu3O7-x (YBCO) films were prepared on LaAlO3 (100) substrate using a low-fluorine sol-gel method. The effect of the oxygen content during firing YBCO films at 725 °C on the critical current density (Jc) of the resulting YBCO films were investigated. It is found that all the YBCO films fired in the oxygen content scale of 100~1700 ppm exhibit good biaxial-texture characteristics. However, the YBCO film is less dense when the oxygen content is low and thus the critical current density (Jc) of the film is inferior. The film surface becomes denser with increasing the oxygen content during the firing process, and Jc of the film reaches 4.3 MA/cm2 when the oxygen content is elevated to 300 ppm. Furthermore, many copper-rich second phases appear on the films surfaces and become more gradually with the further elevating the oxygen content, resulting in the decline of Jc.

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武传宝,赵高扬,房坡,雷黎,李成山.采用低氟溶胶-凝胶法在725℃煅烧温度下制备YBCO超导薄膜的研究[J].稀有金属材料与工程,2016,45(10):2534~2538.[Wu Chuanbao, Zhao Gaoyang ,Fang Po, Lei Li, Li Chengshan. Preparation of YBa2Cu3O7-x Films at the Firing Temperature of 725 °C by a Low-Fluorine Sol-Gel Method[J]. Rare Metal Materials and Engineering,2016,45(10):2534~2538.]
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  • 收稿日期:2015-08-07
  • 最后修改日期:2016-01-14
  • 录用日期:2016-02-24
  • 在线发布日期: 2016-11-10
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