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原位生成WC/TaC复合激光熔覆层组织研究
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上海交通大学 机械与动力工程学院,哈尔滨工业大学 先进焊接与连接国家重点实验室,上海交通大学 机械与动力工程学院,上海交通大学 机械与动力工程学院,上海交通大学 机械与动力工程学院

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国家自然科学基金项目(面上项目,重点项目,重大项目)


In-situ synthesis of WC/TaC reinforced nickel-based composite alloy coating by laser cladding
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School of Mechanical Engineering,Shanghai Jiao Tong University,State Key Lab of Advanced Welding and Joining,Harbin Institute of Technology,Harbin,,School of Mechanical Engineering,Shanghai Jiao Tong University,School of Mechanical Engineering,Shanghai Jiao Tong University

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    摘要:

    利用激光熔覆技术,将氧化钽和石墨的混合粉末添加到Ni60包WC的镍基合金粉末中,成功制备了TaC/WC复合涂层。使用扫描电镜(SEM)、X射线衍射仪(XRD)等仪器分析了镍基合金复合涂层横断面的显微组织,并对其硬度进行研究分析。结果显示在基体与涂层之间形成了良好的冶金结合,复合涂层不仅含有γ-Ni树枝晶、W2C、M7C3、以及大量的弥散分布的TaC颗粒。复合涂层的硬度可达HV965,是Ni60涂层的1.3倍,主要是因为TaC颗粒的分布促使其内部组织结构改变以及相变引起的硬度上升。

    Abstract:

    An in-situ synthesized WC/TaC reinforced nickel-based composite coatings have been fabricated on AISI 1045 mild carbon steel substrate by laser cladding of powder mixture of Ni60/WC with Ta2O5 and graphite. The microstructure and hardness distribution of WC/TaC/Ni60 composite coating are investigated utilizing scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. It is shown that the microstructure of coating has a metallurgical bonding with substrate and is mainly composed of γ-Ni dendrites, W2C, M7C3 carbides, and dispersed TaC particles. The hardness of WC/TaC/Ni60 composite coating has been enhanced to a value similar to that of HV965, which is 1.3 times higher than Ni60 coating. Measurement results demonstrated that these improvements are attributed to the presence of in-situ synthesized TaC particles, microstructure change and phase variations.

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雍耀维,傅卫,张翔,邓琦林,杨建国.原位生成WC/TaC复合激光熔覆层组织研究[J].稀有金属材料与工程,2017,46(11):3176~3181.[Yong Yaowei, Fu Wei, zhang xiang, Deng Qilin, Yang Jianguo. In-situ synthesis of WC/TaC reinforced nickel-based composite alloy coating by laser cladding[J]. Rare Metal Materials and Engineering,2017,46(11):3176~3181.]
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  • 收稿日期:2015-12-01
  • 最后修改日期:2016-02-03
  • 录用日期:2016-02-24
  • 在线发布日期: 2017-12-13
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