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HCA材料的制备与应用
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昆明理工大学化学工程学院,昆明理工大学化学工程学院,昆明贵研催化剂有限公司,昆明贵研催化剂有限公司

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国家重点新产品 ( 2011EG115008)


Preparation and Application of the HCA Catalyst Materials
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Faculty of Chemical Engineering,Kunming University of science and technology,Faculty of Chemical Engineering,Kunming University of science and technology,Kunming Sino-Platinum Metals Catalyst CoLtd,Kunming Sino-Platinum Metals Catalyst CoLtd

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    摘要:

    为满足越来越严格的汽车尾气排放标准且有效降低冷启动时THC排放以及解决神龙、奇瑞车型在冷启动时钯基催化剂的碳氢吸附性能消失的缺点,本文重点探究了所制备的HCA催化剂在发动机台架上的催化性能、HC吸附性能以及其在整车上的应用。在本研究中,采用沸石和贵金属连接体的Pd /Ce-HZSM-5为HCA材料的主要组分,对神龙和奇瑞车型而言,其排放结果表明:冷启动时,Pd/ Ce-HZSM-5型HCA催化剂对HC捕集效果明显优于传统方式制备的催化剂,由于钯基催化剂具有良好的起燃特性,碳氢吸附的连接体及低起燃性使得Pd/Ce-HZSM-5催化剂的碳氢排放进一步减少。冷启动20-30s时,沸石负载钯基催化剂的碳氢吸附量最大。HCA材料对于满足高标准的低温HC排放质量方面具有很大的研究潜力。

    Abstract:

    To meet the Chinese GB regulations (Equivalent to Euro V) and to adsorb the excess hydrocarbons emitted during a period of engine cold-start, in addition, Hydrocarbon (HC) adsorption behavior on Pd-based catalyst appeared during a cold-start period of actual driving cycle in the vehicles of, Dragon and Cherry, therefore, we leaded in HCA (Hydrocarbon Absorber) material. Catalytic performance of prepared HCA catalyst and HC adsorption process were tested, and then their applications were studied in the whole vehicle. In this work, Pd /Ce-HZSM-5 was used as the main recipes of HCA materials as well as a combination of zeolite and precious metals. For Dragon and Cherry models, their emission results show Pd/Ce-HZSM-5 catalyst is superior to conventional catalyst for HC trap. Since Pd-based catalyst showed relatively good light-off performance, the combination of HC adsorption and early light-off activity has led to an improvement of overall HC emission reduction to Pd/Ce-HZSM-5. Use of zeolite combined with Pd-based catalyst caused maximize HC adsorption between 20-30 s during the cold-start period at fresh. HCA material has great research potential to meet high standards of HC emissions quality at low temperature.

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阳超琴,王亚明,吴乐刚,李文松. HCA材料的制备与应用[J].稀有金属材料与工程,2017,46(9):2423~2427.[YANG Chaoqin, WANG Yaming, WU Legang, LI Wensong. Preparation and Application of the HCA Catalyst Materials[J]. Rare Metal Materials and Engineering,2017,46(9):2423~2427.]
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  • 收稿日期:2015-12-30
  • 最后修改日期:2017-09-09
  • 录用日期:2016-12-06
  • 在线发布日期: 2017-11-29
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