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SLM-Ti仿生微纳米复合结构超疏水表面的构建
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1.广州中国科学院先进技术研究所;2.广东水利电力职业技术学院;3.辽宁科技大学

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广东省产学研协同创新基金资助(项目号2017B090901039);广东省自然科学基金项目(项目号2019A1515011272);广东省科技计划项目(2019A050516001);深圳市基础研究项目(JCYJ20170818154539480)


Preparation of biomimetic superhydrophobic micro- and nanophotography on selective laser melted titanium
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1.Guangzhou Institutes of Advanced technology,Chinese Academy of Sciences;2.Guangdong Technical College of Water Resources and Electric Engineering

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    摘要:

    本文以选区激光熔化技术制备的金属钛为基体,采用阳极氧化法在SLM-Ti表面微米级球形“模板”上一步制备仿生微纳米复合结构。结果表明,未经紫外光照或高温处理的SLM-TiO2纳米管在经全氟辛基三乙氧硅烷(1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane molecules, POTS)修饰后即获得了超疏水表面,其静态水接触角达≈163.8°,滚动角<1°。对比分析了阳极氧化后商用纯钛CP-TiO2和SLM-TiO2的表面形貌特征和POTS修饰后的静态/动态水接触角。测得POTS修饰后的CP-TiO2和SLM-TiO2表面静态水接触角分别为≈149.0°和≈163.8°,即二者均显现出静态超疏水特性。但在有自清洁、防水、防污特性要求时,材料表面的动态接触角才是更为重要的参数,相同条件下获得的CP-TiO2表面在倾斜至90°后水滴依然粘附在材料表面,而SLM-TiO2表面水滴在倾斜不足1°时即快速地(155ms内)从材料表面滚落。

    Abstract:

    In this paper, the biomimetic micro- and nanotopography was fabricated in one step on the micron scale spherical "template" of SLM-Ti substrate by anodic oxidation technology. The results show that the TiO2 nanotubes arrays on SLM-Ti substrate without UV irradiation or high-temperature treatment exhibit superhydrophilic property after being modified with 1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane molecules. The morphology and static/dynamic water contact angle of POTS modified CP-TiO2 and SLM-TiO2 were compared and analyzed. The measured static contact angles of CP-TiO2 and SLM-TiO2 are ?149° and ?163.8° respectively, indicating that both of them are close to the superhydrophobic standard. However, the dynamic contact angle is the more important factor when self-cleaning, waterproof and anti-fouling characteristics are required. The results show that the water droplet was pinned on the CP-TiO2 surface when the surface was tilted vertically, while the droplet on SLM- TiO2 surface rolled off quickly within 155ms when the surface was tilted less than 1°.

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刁桂林,孙学通,林怀抒,李雪,金建,邸思. SLM-Ti仿生微纳米复合结构超疏水表面的构建[J].稀有金属材料与工程,2021,50(6):2144~2148.[Diao Guilin, Sun Xuetong, Lin Huaishu, Li Xue, Jin Jian, Di Si. Preparation of biomimetic superhydrophobic micro- and nanophotography on selective laser melted titanium[J]. Rare Metal Materials and Engineering,2021,50(6):2144~2148.]
DOI:10.12442/j. issn.1002-185X.20200514

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历史
  • 收稿日期:2020-07-17
  • 最后修改日期:2020-09-03
  • 录用日期:2020-09-18
  • 在线发布日期: 2021-07-07
  • 出版日期: 2021-06-30