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孔特性可控的轻质YSZ泡沫陶瓷制备及其力学性能研究
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1.江西科技师范大学;2.中国科学院上海硅酸盐研究所

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国家自然科学基金(51862009);江西省科技厅自然科学基金(20202BABL204016);江西省教育厅科技类重点项目(GJJ190585);校级青年拔尖人才项目(2018QNBJRC005); 大学生创新训练计划项目(20201404089)


Research on fabrication and mechanical properties of lightweight YSZ ceramicfoams with controllable cell structure
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    摘要:

    采用颗粒稳定泡沫的方法制备出闭孔结构、孔径均匀分布和轻质的氧化钇稳定的氧化锆(YSZ)泡沫陶瓷。研究烧结温度、表面活性剂种类和固含量对泡沫陶瓷骨架组成、孔特性(包括孔隙率、孔径分布和平均孔径)和压缩强度的影响规律。结果显示,孔隙率处于45-85 %之间时,YSZ泡沫陶瓷的压缩强度与孔隙率之间的关系符合Rice模型;在1450 ℃烧结温度及固含量为32.50 vol%时,采用异丁烯与马来酸酐共聚物分子和阳离子型表面活性剂十二烷基三甲基氯化铵共稳YSZ湿泡沫制备出的材料综合性能最优,孔隙率为83.7±0.2 %、平均孔径90.1±0.8 μm、压缩强度45.1±1.3 MPa。在相同孔隙率的情况下,YSZ泡沫陶瓷的压缩强度高于大多数已报道的结果。

    Abstract:

    The particle-stabilized foams method was successfully applied to fabricate the lightweight YSZ ceramic foams with closed pore structure and uniform pore size distribution. The microstructure of YSZ ceramic foams, including strut structure, porosity, mean pore size and pore size distribution were tailored by varying the sintering temperature, surfactant type and solid content of the initial slurries. When the sintering temperature at 1450 ℃ and solid content 32.50 vol%, YSZ ceramic foams with porosity of 83.7±0.2 %, mean pore size of 90.1±0.8 μm and compressive strength of 45.1±1.3 MPa were obtained through Isobam molecule and cationic surfactant dodecyl trimethyl ammonium chloride (DTAC) co-stabilized YSZ wet foam. The compressive strength of YSZ ceramic foams in present work was much higher than most reported results in the case of same porosity.

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艾建平,李萌,周国红,江博帆,胡丽玲,王正娟,李文魁.孔特性可控的轻质YSZ泡沫陶瓷制备及其力学性能研究[J].稀有金属材料与工程,2022,51(3):1072~1080.[Ai Jianping, Li Meng, Zhou Guohong, Jiang Bofan, Hu Liling, Wang Zhengjuan, Li Wenkui. Research on fabrication and mechanical properties of lightweight YSZ ceramicfoams with controllable cell structure[J]. Rare Metal Materials and Engineering,2022,51(3):1072~1080.]
DOI:10.12442/j. issn.1002-185X.20210247

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  • 收稿日期:2021-03-23
  • 最后修改日期:2021-05-22
  • 录用日期:2021-06-21
  • 在线发布日期: 2022-04-06
  • 出版日期: 2022-03-30