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铒元素对锆基合金的非晶形成能力及力学性能的影响
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作者单位:

1.兰州理工大学 材料科学与工程学院,甘肃 兰州 730050;2.兰州理工大学 省部共建有色金属先进加工与再利用国家重点实验室,甘肃 兰州 730050;3.兰州理工大学 机电工程学院,甘肃 兰州 730050

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中图分类号:

TG139

基金项目:

国家自然科学基金项目(51971103,51861021);甘肃省重点研发计划项目资助(20YF8GA052))


Effect of Er on Amorphous Forming Ability and Mechanical Properties of Zr-based Alloys
Author:
Affiliation:

1.School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China;2.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China;3.School of Mechanical and Electrical Engineering, Lanzhou University of Technology, Lanzhou 730050

Fund Project:

National Natural Science Foundation of China (51971103, 51861021); Key R&D Program of Gansu Province (20YF8GA052)

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    摘要:

    以海绵锆为原料,采用水冷铜坩埚熔炼和铜模吸铸法制备了直径为3 mm、成分为(Zr0.55Cu0.3Al0.1Ni0.05)100-xErx (x=0,0.5,1,2,3,4,5)的锆基块体合金,通过对比不同铒含量海绵锆基合金的组织结构与性能,研究了铒元素对其非晶形成能力、热稳定性和力学性能的影响。结果表明:以海绵锆为原料时,锆基合金的非晶形成能力和力学性能明显下降。x=0时,无法制备成锆基非晶合金;添加Er元素后,海绵锆基合金的非晶形成能力和力学性能显著提高,具有非晶态结构;x=2时,海绵锆基非晶合金的力学性能最优,抗压强度σbc为2142.5 MPa,室温下塑性应变εp为10.01%。与高纯锆制备的同直径(Zr0.55Cu0.3Al0.1Ni0.05)98Er2非晶合金相比,其抗压强度恢复97.63%,室温塑性恢复69.95%。添加铒元素有利于改善和提高海绵锆基合金的非晶形成能力和力学性能,为低成本制备锆基非晶合金提供一种新思路。

    Abstract:

    The (Zr0.55Cu0.3Al0.1Ni0.05)100-xErx (x=0, 0.5, 1, 2, 3, 4, 5) Zr-based bulk alloy with diameter of 3 mm was prepared by water-cooled copper crucible smelting and copper mold suction casting using zirconium sponge as raw material. By comparing the microstructure and mechanical properties of sponge Zr-based alloy with different Er contents, the influence of Er on the amorphous forming ability, thermal stability, and mechanical properties of Zr-based bulk alloy was studied. Results show that when the zirconium sponge is used as the raw material, the amorphous formation ability and mechanical properties of sponge Zr-based alloy are obviously reduced. The sponge Zr-based amorphous alloy cannot be prepared when x=0. After adding Er element, the amorphous forming ability and mechanical properties of the sponge Zr-based alloy with the amorphous structure are improved obviously. The optimal mechanical properties of the sponge Zr-based alloy are achieved when x=2: the compression strength σbc is 2142.5 MPa and the plastic strain εp is 10.01% at room temperature. Compared with the amorphous (Zr0.55Cu0.3Al0.1Ni0.05)98Er2 alloy with the diameter of 3 mm prepared from high-purity Zr, the compressive strength and plasticity at room temperature of the sponge Zr-based alloy recovers by 97.63% and 69.95%, respectively. The Er addition is beneficial to improve the amorphous forming ability and mechanical properties of sponge Zr-based alloy, which also provides a new approach for low-cost preparation of Zr-based amorphous alloy.

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付小强,寇生中,李晓诚,丁瑞鲜,李春燕,李春玲.铒元素对锆基合金的非晶形成能力及力学性能的影响[J].稀有金属材料与工程,2022,51(9):3159~3165.[fuxiaoqiang, koushengzhong, lixiaocheng, dingruixian, lichunyan, lichunling. Effect of Er on Amorphous Forming Ability and Mechanical Properties of Zr-based Alloys[J]. Rare Metal Materials and Engineering,2022,51(9):3159~3165.]
DOI:10.12442/j. issn.1002-185X.20210673

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历史
  • 收稿日期:2021-07-26
  • 最后修改日期:2021-09-09
  • 录用日期:2021-09-09
  • 在线发布日期: 2022-09-30
  • 出版日期: 2022-09-27