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快淬速度及热处理对Nd26Pr3FebalCo4Ga0.42B0.92快淬薄带微观结构和磁性的影响
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钢铁研究总院功能材料研究所

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国家自然科学基金资助(项目号51771055);宁波市科技创新2025重大专项资助(项目号2019B10093)


Effects of melt-spunning speed and heat treatment on the magnetic properties and microstructure of Nd26Pr3FebalCo4Ga0.42B0.92 melt-spun ribbons.
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Central Iron Steel Research Institute

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    摘要:

    研究了快淬速度(v=15、20、25、30和35 m/s)和热处理对熔体快淬法制备的成分为Nd26Pr3FebalCo4Ga0.42B0.92的快淬薄带的微观结构和磁性能的影响。v<25m/s 时,薄带自由面具有明显的取向,c轴垂直于薄带表面;随着快淬速度的提升,取向度明显降低。提高快淬速度可以细化晶粒,提升至v>25 m/s以上时非晶含量明显提升,当v<25 m/s时初始磁化曲线表现为一步磁化过程,退磁曲线的方形度较好;当v>25 m/s时向两步磁化转变,退磁曲线出现明显塌腰;在v=25 m/s时取得最佳磁性能,分别为Br=0.91T,μ0Hcj=1.70 T,(BH)max=108.22 kJ/m3。对快淬薄带进行适当的晶化退火处理后,快淬带中的非晶含量显著减少,v≤25 m/s的快淬薄带的磁性能有所改善;v>25 m/s时退磁曲线塌腰消失,矫顽力大幅提升,方形度明显改善;在v=35 m/s制备的快淬薄带取得最高矫顽力,μ0Hcj = 2.10 T;v=30 m/s时取得最佳磁性能,分别为Br=0.91T,μ0Hcj=1.82 T,(BH)max=141.61 kJ/m3。快淬薄带形貌沿厚度方向变化,热处理前其贴辊面一侧以非晶及细晶为主,自由面晶粒较大;热处理后贴辊面一侧的非晶含量显著减少。

    Abstract:

    The effects of melt-spinning speed(v=15,20,25,30 and 35 m/s, respectively) and heat-treatment process on the magnetic properties and microstructure of melt-spun Nd26Pr3FebalCo4Ga0.42B0.92 ribbons were investigated. The ribbons show an obvious orientation when the speed v is less than 25m/s in the free side,which c-axis is perpendicular to the strip surface;the orientation decreases with the increase of melt-spinning speed. The grain can be refined by increasing the melt-spinning speed,when v < 25 m/s, the amorphous content increases obviously, the initial magnetization shows a one-step magnetization process,which demagnetization curve have good squareness;When v > 25 m / s, the initial magnetization changes to two-step magnetization process, and the demagnetization curve collapses obviously; The best magnetic properties are obtained when v=25 m/s,Br=0.91T,μ0Hcj=1.70 T,(BH)max=108.22 kJ/m3, After optimum crystallization annealing treatment, the amorphous content reduce significantly;all of the magnetic properties of ribbons have improved,the v>25 m/s imporve obviously, squareness and coercivity improve remarkable.The ribbon prepared at v=35m/s get the highest coercivity, μ0Hcj=2.10 T.The best magnetic properties are obtained when v=30 m/s,Br=0.91T,μ0Hcj=1.82 T,(BH)max=141.65 kJ/m3,The microstructure changes along with the thickness direction.The wheel side is composed of amorphous and fine grains,the free side is composed by larger grains.After the heat-treatment,the amorphous is reduced significantly.

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苑子凯,郭朝晖,王俊明,钟雨江,柳帅,朱明刚.快淬速度及热处理对Nd26Pr3FebalCo4Ga0.42B0.92快淬薄带微观结构和磁性的影响[J].稀有金属材料与工程,2022,51(6):2273~2279.[YUAN Zikai, GUO Zhaohui, WANG Junming, ZHONG Yujiang, LIU Shuai, ZHU Minggang. Effects of melt-spunning speed and heat treatment on the magnetic properties and microstructure of Nd26Pr3FebalCo4Ga0.42B0.92 melt-spun ribbons.[J]. Rare Metal Materials and Engineering,2022,51(6):2273~2279.]
DOI:10.12442/j. issn.1002-185X.20210877

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  • 收稿日期:2021-10-10
  • 最后修改日期:2022-01-02
  • 录用日期:2022-01-29
  • 在线发布日期: 2022-07-06
  • 出版日期: 2022-06-29