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碳纳米管对Ag-Cu-Ti焊料组织与性能的影响
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1.郑州机械研究所有限公司;2.江苏师范大学 机电工程学院

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河南省特聘研究员项目


Effect of CNTs on the Microstructure and Properties of Ag-Cu-Ti Filler Metal
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1.Zhengzhou Research Institute of Mechanical Engineering Co,LTD;2.School of Mechatronic Engineering,Jiangsu Normal University

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    摘要:

    Ag-Cu-Ti合金作为活性焊料可以实现金属-金刚石连接,研究了碳纳米管(CNTs)对Ag-Cu-Ti焊料组织和性能的影响。结果表明:添加碳纳米管可以明显降低焊料在钢基板表面的润湿铺展面积,焊料的熔化温度可以提高~9℃,显著提高焊点的剪切强度,当纳米管添加量为0.2%时,剪切强度达到最大值,提高幅度达49.3%。对Ag-Cu-Ti-xCNTs焊料组织SEM分析,发现碳纳米管(≤0.1%)显著细化焊料基体组织,过量的碳纳米管导致焊料组织明显粗化。对Ag-Cu-Ti-xCNTs焊点断口形貌进行分析,Ag-Cu-Ti-xCNTs(x=0.05%, 0.1%, 0.2%, 0.5%)焊点呈现明显的韧性断裂特征,Ag-Cu-Ti和Ag-Cu-Ti-1.0CNTs焊点则表现出明显的混合断裂特征。

    Abstract:

    Ag-Cu-Ti alloy can be used as active filler metal to achieve metal-diamond bonding, the effect of CNTs on the microstructure and properties of Ag-Cu-Ti filler metal was investigated. The results indicate that CNTs can improve the wetting spreading area of filler metal on the surface of steel substrate, and increase the melting temperature with ~9℃, and obviously increase the shear strength of brazed joint, when the content of CNTs is 0.2%, the maximum shear strength can be obtained with 49.3% amplitude. Moreover, SEM figures indicate that the addition of CNTs can refine the microstructure of filler metal, but excessive CNTs would coarsen the microstructure of Ag-Cu-Ti. For the fracture morphologies of Ag-Cu-Ti-xCNTs brazed joints, obvious ductile fracture mode can be observed on the fracture surface of Ag-Cu-Ti-xCNTs (x=0.05%, 0.1%, 0.2%, 0.5%) brazed joints. however, The fracture mechanism of Ag-Cu-Ti and Ag-Cu-Ti-1.0CNTs brazed joints shows obvious mixed fracture mode.

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张 亮,龙伟民,钟素娟,李志豪,李木兰.碳纳米管对Ag-Cu-Ti焊料组织与性能的影响[J].稀有金属材料与工程,2022,51(9):3492~3496.[Zhang Liang, Long Weimin, Zhong Sujuan, Li Zhihao, Li Mulan. Effect of CNTs on the Microstructure and Properties of Ag-Cu-Ti Filler Metal[J]. Rare Metal Materials and Engineering,2022,51(9):3492~3496.]
DOI:10.12442/j. issn.1002-185X.20220051

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  • 收稿日期:2022-01-18
  • 最后修改日期:2022-04-29
  • 录用日期:2022-05-26
  • 在线发布日期: 2022-10-08
  • 出版日期: 2022-09-27