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预变形对Cu-6 wt%Ag合金时效析出及性能的影响
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东北大学材料电磁过程研究教育部重点实验室

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国家重点研发计划 (项目号:2017YFE0107900),国家111计划2.0(项目号:BP0719037)


Influence of pre-deformation on aging precipitation and mechanical properties of Cu-Ag alloy
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Key Laboratory of Electromagnetic Processing of Materials Ministry of Education,Northeastern University,Shenyang

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    摘要:

    Cu-Ag合金是具有重要应用前景的高强高导合金,其形变加工和热处理工艺的改进对性能的进一步提高具有重要作用,但热处理前预形变的作用一直未受重视。本文通过XRD物相分析、维氏硬度、电导率、金相显微镜和扫描电镜等方法,研究了预变形对固溶+时效处理的Cu-6 wt%Ag合金组织和性能的影响。结果表明,预变形促使Cu-6Ag合金发生再结晶,晶粒尺寸明显降低。同时,预变形降低了时效处理后Cu-6 wt%Ag合金的固溶量。预变形+时效处理的样品与未进行预变形的样品中均观察到非连续性析出相。预变形合金中的非连续析出相间距更小,为95±9.5nm。预变形合金的硬度稍低于未预变形合金,为85.8 HV,导电率与未预变形合金基本持平,为90.3 % IACS。

    Abstract:

    Cu-Ag alloy is a kind of high-strength and high-conductivity alloy with important application prospects. The improvement of the properties of Cu-Ag alloy depends on the development of the deformation and heat-treatment process. However, the effect of pre-deformation before the heat treatment has not been investigated. The effects of pre-deformation on microstructure and properties after solid solution were investigated using XRD analysis, Vickers hardness, conductivity, metalloscope and scanning electron microscopy. The results show that pre-deformation promotes the recrystallization of Cu-6Ag alloy, and the grain size is obviously reduced. Meanwhile, the pre-deformation reduces the amount of Ag in Cu-6 wt% Ag alloy after aging treatment. Discontinuous precipitates are observed in samples with or without pre-deformation. The discontinuous precipitation in the pre-deformed alloy has a smaller spacing of 95±9.5nm. The hardness in pre-deformation alloy is 85.8 HV lower than that in unpre-deformation alloy. The conductivity of pre-deformed alloy is almost equal to unpre-deformation alloy which is, 90.3%IACS.

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杜靖文,安佰灵,张林,王恩刚.预变形对Cu-6 wt%Ag合金时效析出及性能的影响[J].稀有金属材料与工程,2023,52(1):403~408.[Du Jingwen, An Bailing, Zhang lin, Wang Engang. Influence of pre-deformation on aging precipitation and mechanical properties of Cu-Ag alloy[J]. Rare Metal Materials and Engineering,2023,52(1):403~408.]
DOI:10.12442/j. issn.1002-185X.20220329

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  • 收稿日期:2022-04-19
  • 最后修改日期:2022-08-28
  • 录用日期:2022-09-22
  • 在线发布日期: 2023-02-13
  • 出版日期: 2023-02-08