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W-Fe-C复合材料的低温致密化机制及力学性能
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武汉理工大学 材料复合新技术国家重点实验室

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国家自然科学基金(52171045、52401163);湖北自然科学基金(224AFB733)


Low-Temperature Preparation and Densification Mechanism of W-Fe-C Composites
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State Key Laboratory of Advanced Technology for Materials Synthesis and Processing,Wuhan University of Technology

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the National Natural Science Foundation of China [52171045、52401163], Hubei Provincial Natural Science Foundation of China [2024AFB733]

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    摘要:

    采用放电等离子烧结(SPS)在不同烧结温度下制备W-Fe-C复合材料,对其烧结行为、物相组成、微观形貌以及力学行为进行表征,并分析了其致密化机理。结果表明,随温度升高,复合材料中增强相由Fe6W6C转变为Fe3W3C,最终变为Fe2W2C。1400 ℃烧结后,样品相对密度高达99.2%,极限压缩强度为2455.15 MPa,变形率为25.42%。W-Fe-C复合材料在保温阶段存在一个特殊的蠕变恢复阶段,此阶段致密化速率几乎为零。W-Fe-C复合材料有效应力指数()值约为 1 和 2 时,活化能估计分别为341.27 和 1005.73 kJ/mol,高于纯W,但由于原位反应促进扩散,其相对密度高于纯W。本研究为低温制备钨基复合材料提供了新思路。

    Abstract:

    The W-Fe-C composites were prepared using spark plasma sintering (SPS) at various sintering temperatures, and their sintering behavior, phase composition, microstructure, and mechanical properties were characterized. The densification mechanism was also analyzed. The results show that as the temperature increases, the reinforcement phase in the composite transitions from Fe?W?C to Fe?W?C, and finally to Fe?W?C. After sintering at 1400 °C, the sample achieved a relative density of 99.2%, with an ultimate compressive strength of 2455.15 MPa and a deformation rate of 25.42%. During the holding stage, the W-Fe-C composite exhibited a unique creep recovery stage, where the densification rate was nearly zero. When the effective stress exponent (n) was approximately 1 and 2, the estimated activation energies were 341.27 and 1005.73 kJ/mol, respectively, which are higher than that of pure tungsten. However, due to the in-situ reaction promoting diffusion, the relative density of the W-Fe-C composites exceeded that of pure tungsten. This study provides a new approach for the low-temperature fabrication of tungsten-based composites.

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张建,成禹,李佳琪,魏琴琴,欧阳迪,罗国强. W-Fe-C复合材料的低温致密化机制及力学性能[J].稀有金属材料与工程,,().[Zhang Jian, Cheng Yu, Li Jiaqi, Wei Qinqin, Ou Yangdi, Luo Guoqiang. Low-Temperature Preparation and Densification Mechanism of W-Fe-C Composites[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-12-19
  • 最后修改日期:2025-02-21
  • 录用日期:2025-03-03
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