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FeCrxMnAlCu高熵合金在3.5 wt.% NaCl溶液中耐腐蚀性能的影响
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兰州理工大学材料科学与工程学院

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甘肃省第四批拔尖人才(ZZ2023G50100013),甘肃省科技重大专项计划(24ZDWA008)


Corrosion behaviors of FeCrxMnAlCu high-entropy alloys ina 3.5 wt.% NaCl solution
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School of Material Science and Technology,Lanzhou University of Technology

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The authors gratefully appreciate the financial supports from the fourth batch of top leading talents fund projects in Gansu Province (ZZ2023G50100013),The Gansu Provincial Science and Technology Major Special Program (24ZDWA008)

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    摘要:

    在本研究中,采用真空电弧熔炼制备FeCr?MnAlCu(x=0,0.5,1.0,1.5,2.0)高熵合金,通过电化学动电位极化曲线和浸泡实验的方法研究了该合金在室温下3.5 wt.% NaCl溶液中的腐蚀行为。微观组织结果表明,Cr0合金具有BCC相结构,而Cr0.5至Cr2.0高熵合金具有FCC+BCC双相混合结构。腐蚀结果表明,随着Cr含量的增加,高熵合金的耐蚀性增加。其中,Cr2.0高熵合金表现出最佳的耐腐蚀性能,具有最高的自腐蚀电位(Ecorr = - 0.354 V vs Ag/AgCl)和最小的自腐蚀电流密度(Icorr=1.991×10-6 A?cm-2)和最小的腐蚀速率(0.0292 mm/a)。XPS拟合结果表明,在腐蚀后的高熵合金表面形成了氧化物和氢氧化物的复合钝化膜,且Cr2O3含量随着Cr含量的增加而增加,从而有效地提高了钝化膜的稳定性和保护性能。

    Abstract:

    In this study, FeCr?MnAlCu (x=0, 0.5, 1.0, 1.5, 2.0) high-entropy alloys were fabricated using vacuum arc melting and the corrosion behavior of the alloy in 3.5 wt.% NaCl solution at room temperature was investigated by means of electrochemical dynamic potential polarization curves and immersion experiments. The microstructure results show that Cr0 alloys formed a BCC phase structure, while Cr0.5 to Cr2.0 high entropy alloys formed a mixed FCC+BCC dual-phase structure. The corrosion results show that the corrosion resistance of the high-entropy alloy increases with the increase of Cr content. Among them, the Cr2.0 high-entropy alloy exhibited the best corrosion resistance with the highest selfcorrosion potential (Ecorr = - 0.354 V vs Ag/AgCl) and the smallest self-corrosion current density (Icorr = 1.991×10-6 A?cm-2) and the smallest corrosion rate (0.0292 mm/a). The XPS fitting results show that a composite passivation film of oxides and hydroxides was formed on the surface of the corroded high-entropy alloy, and the Cr2O3 content increases with the increase of Cr content, which effectively improves the stability and protective properties of the passivation film.

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冯力,张娴,马凯,赵燕春,苓亚军,刘瑞龙,付轩. FeCrxMnAlCu高熵合金在3.5 wt.% NaCl溶液中耐腐蚀性能的影响[J].稀有金属材料与工程,,().[Feng Li, Zhang Xian, Ma Kai, Zhao Yanchun, Ling Yajun, Liu Ruilong, Fu Xuan. Corrosion behaviors of FeCrxMnAlCu high-entropy alloys ina 3.5 wt.% NaCl solution[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2025-02-08
  • 最后修改日期:2025-03-18
  • 录用日期:2025-03-20
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