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放电等离子烧结Ti-47.5Al-6.8Nb-0.2W-xY合金高温压缩蠕变行为及机理研究
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1.桂林电子科技大学 材料科学与工程学院;2.哈尔滨工业大学 材料科学与工程学院;3.西北工业大学 材料科学与工程学院

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国家自然科学基金(52161011);广西重点研发计划(桂科 AB23026114);广西信息材料重点实验室基金(221030-Z)


Study on the High Temperature Compression Creep Behaviour and Mechanism ofTi-47.5Al-6.8Nb-0.2W-xY Alloy by Spark Plasma Sintering
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1.School of Materials Science and Engineering,Guilin University of Electronic Technology;2.School of Materials Science and Engineering,Harbin Institute of Technology

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    摘要:

    采用高能球磨(High - energy Ball Milling,HEM)和放电等离子烧结(Spark Plasma Sintering,SPS)工艺制备Ti-47.5Al-6.8 Nb-0.2W-xY(x=0,0.1,0.2at.%)合金,通过SEM、EBSD、TEM等研究Y微合金化对Ti-47.5Al-6.8 Nb-0.2W合金高温压缩蠕变性能的影响,分别在800~850 ℃进行蠕变试验,应力为250 MPa,时间为50 h。结果表明:Ti-47.5Al-6.8Nb-0.2W-xY合金均由等轴γ晶粒、γ晶界的块状α2和B2相、α2/γ片层团组成。添加的Y主要以Al2Y颗粒的形式在晶界处形成链状结构,Y能细化晶粒并增大α2/γ片层团,Y含量由0增至0.2时,晶粒尺寸从12.1 μm减小至7.8 μm,细化效果最为显著。在蠕变后合金中γ晶粒轻微扁平化,片层发生弯曲和退化现象,片层团内部出现大量细小的再结晶晶粒及球状B2相,蠕变温度升高促进动态再结晶形成。Y的加入显著提高合金的压缩蠕变性能,在800 ℃下,0.2Y合金的最大蠕变应变为8.96%,最小蠕变速率为4.01×10-7 s-1,与无Y合金相比分别降低了48.88%和62.09%。合金力学性能的改善是由于Al2Y颗粒的第二相强化、片层细化和B2相的减少。

    Abstract:

    Ti-47.5Al-6.8 Nb-0.2W-xY (x=0,0.1,0.2 at.%) alloys were prepared by high - energy ball milling and spark plasma sintering processes, and the effects of Y microalloying on the high temperature compression creep properties of Ti-47.5Al-6.8 Nb-0.2W alloys were investigated by SEM, EBSD and TEM. Creep experiments were carried out at 800~850 ℃, with a stress of 250 MPa and a time of 50 h. The results show that the Ti-47.5Al-6.8Nb-0.2W-xY alloys are all composed of equiaxial γ grains, γ grain boundaries of the bulk α2 and B2 phases, α2/γ lamellar colonies .The added Y is mainly in the form of Al2Y particles at the grain boundaries to form a chain structure, Y can refine the grains and increase the α2/γ lamellar colonies, when the Y content was increased from 0 to 0.2, the grain size was reduced from 12.1 μm to 7.8 μm, with the most significant refining effect. After creep in the alloy γ grains slightly flattened, lamellar bending and degradation phenomenon, lamellar clusters within the appearance of a large number of fine recrystallised grains and spherical B2 phase, creep temperature increases to promote the formation of dynamic recrystallisation. The addition of Y significantly improves the compressive creep properties of the alloy. At 800 ℃, the maximum creep strain of the 0.2Y alloy is 8.96%, and the minimum creep rate is 4.01×10-7 s-1, which is reduced by 48.88% and 62.09%, respectively, compared with that of the alloy without Y. The improvement in the mechanical properties of the alloys was attributed to the precipitation strengthening of the second phase Al2Y particles, lamellar refinement and reduction of the B2 phase.

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于宏宝,周宇君,于红艳,肖树龙,唐斌,卢照.放电等离子烧结Ti-47.5Al-6.8Nb-0.2W-xY合金高温压缩蠕变行为及机理研究[J].稀有金属材料与工程,,().[Yu Hongbao, Zhou Yujun, Yu Hongyan, Xiao Shulong, Tang Bin, Lu Zhao. Study on the High Temperature Compression Creep Behaviour and Mechanism ofTi-47.5Al-6.8Nb-0.2W-xY Alloy by Spark Plasma Sintering[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2025-03-21
  • 最后修改日期:2025-05-14
  • 录用日期:2025-05-27
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