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富镍镨掺杂镍钛形状记忆合金的微结构、相变特性与硬度
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包头医学院,内蒙古 包头 014040

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The Natural Science Foundation of Inner Mongolia, grant number 2019BS03010; the PhD Start-up Foundation of Baotou Medical College, grant number BSJJ201808


Effect of Pr Addition on Microstructure, Phase Transforma-tion Behavior, and Hardness of Ni-Rich NiTi Shape Memory Alloy
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Baotou Medical College, Baotou 014040, China

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Natural Science Foundation of Inner Mongolia (2019BS03010); Ph. D. Start-up Foundation of Baotou Medical College (BSJJ201808)

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    摘要:

    采用真空熔炼法向NiTi二元合金中掺杂Pr稀土元素,制备了多组分原子分数的Ni50Ti50-xPrxx=0,0.1,0.3,0.5,0.7,0.9)合金。研究了Pr元素的添加对NiTi合金金相组织、相变温度和硬度的影响。结果表明,Ni50Ti50-xPrx合金由NiTi基体与NiPr夹杂相组成,其中Ni50Ti49.5Pr0.5合金的马氏体相变温度达73 ℃,合金的热滞窄至37 ℃,维氏硬度约为2850 MPa。Pr元素的添加显著降低了NiTi合金的马氏体相变温度,同时,与其他NiTi基合金相比,NiTiPr合金保持了较窄的热滞和较高的硬度。

    Abstract:

    The influence of Pr addition on the microstructure, phase transformation, and hardness of Ni50Ti50-xPrx (x=0, 0.1, 0.3, 0.5, 0.7, 0.9, at%) shape memory alloys was investigated. Results show that Ni50Ti50-xPrx alloys consist of NiTi matrix and NiPr precipi-tates. Ni50Ti49.5Pr0.5 alloy has the optimal properties of martensitic transformation start temperature of 73 °C, the thermal hysteresis as narrow as 37 °C, and the Vickers hardness of 2850 MPa. Pr addition obviously decreases the martensitic transformation temperature of NiTi alloys, but the composite alloy maintains a relatively narrow thermal hysteresis and relatively high Vickers hardness, compared with other NiTi-based shape memory alloys.

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赵石磊,赵昆,王富文.富镍镨掺杂镍钛形状记忆合金的微结构、相变特性与硬度[J].稀有金属材料与工程,2021,50(7):2352~2357.[Zhao Shilei, Zhao Kun, Wang Fuwen. Effect of Pr Addition on Microstructure, Phase Transforma-tion Behavior, and Hardness of Ni-Rich NiTi Shape Memory Alloy[J]. Rare Metal Materials and Engineering,2021,50(7):2352~2357.]
DOI:10.12442/j. issn.1002-185X. E20200030

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历史
  • 收稿日期:2020-07-10
  • 最后修改日期:2020-08-26
  • 录用日期:2020-09-18
  • 在线发布日期: 2021-08-09
  • 出版日期: 2021-07-31