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成分设计优化TiC/Hastelloy复合材料的抗氧化性能
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作者单位:

1.山东科技大学 材料科学与工程学院,山东 青岛 266590;2.中国科学院兰州化学物理研究所 固体润滑国家重点实验室,甘肃 兰州 730000

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基金项目:

山东省自然科学基金ZR2020QE003


Oxidation Resistance Optimization of TiC/Hastelloy Compo-sites by Designing Composition
Author:
Affiliation:

1.School of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China;2.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China

Fund Project:

Natural Science Foundation of Shandong Province (CN) (ZR2020QE003)

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    摘要:

    TiC/Hastelloy复合材料是极具应用前景的中温固体氧化物燃料电池连接体材料,而抗氧化性能是影响其应用的关键性能之一。通过无压反应渗透工艺分别制备出含有50vol%和58vol%金属基体的TiC/Hastelloy复合材料。高金属含量使复合材料中的Cr含量增加,促进连续Cr2O3氧化层的形成,抑制Ni和Ti原子的外扩散,进而优化复合材料的抗氧化性能。氧化膜中Ti和Ni的氧化物含量降低,复合材料的氧化增重由2.03 mg·cm-2降低到0.55 mg·cm-2。同时,为了抑制Cr挥发,在含有58vol%金属基体的TiC/Hastelloy复合材料中引入Co。在氧化过程中,Co和金属基体中的Fe在Cr2O3氧化层中具有较快的扩散速率,可以在Cr2O3氧化层外侧原位形成CoFe2O4层。

    Abstract:

    TiC/Hastelloy composite has been proposed as one of promising intermediate temperature solid oxide fuel cell interconnects, and the oxidation resistance is one key property for its application. TiC/Hastelloy composites with 50vol% and 58vol% metal matrix were prepared by reactive infiltration method. Results show that high metal content results in the increase in Cr content, which optimizes the oxidation resistance of TiC/Hastelloy composites by promoting formation of continuous Cr2O3 layer to inhibit external diffusion of Ni and Ti. The content of Ti and Ni oxides in oxide scale obviously decreases. The mass gain reduces from 2.03 to 0.55 mg·cm-2. Meanwhile, in order to inhibit the migration of Cr, Co is extra introduced into the composites with 58vol% metal. During the oxidation process, Co and Fe (in metal matrix) show high external diffusion rate through Cr2O3, and generate in-situ CoFe2O4 layer outmost the oxide scale.

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齐倩,王鲁杰,宋晓杰.成分设计优化TiC/Hastelloy复合材料的抗氧化性能[J].稀有金属材料与工程,2022,51(6):1999~2004.[Qi Qian, Wang Lujie, Song Xiaojie. Oxidation Resistance Optimization of TiC/Hastelloy Compo-sites by Designing Composition[J]. Rare Metal Materials and Engineering,2022,51(6):1999~2004.]
DOI:10.12442/j. issn.1002-185X. E20210009

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历史
  • 收稿日期:2021-04-14
  • 最后修改日期:2021-09-22
  • 录用日期:2021-09-27
  • 在线发布日期: 2022-06-29
  • 出版日期: 2022-06-29