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磁铅石结构LaMgAl11O19粉体制备及其晶格热膨胀
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武汉科技大学冶金矿产资源高效利用与造块湖北省重点实验室,武汉科技大学省部共建耐火材料与冶金国家重点实验室,,武汉科技大学冶金矿产资源高效利用与造块湖北省重点实验室

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纳米矿物材料及应用教育部工程研究中心开放基金资助(项目号NGM2016KF008)


Preparation and lattice thermal expansion of lanthanum magnesium hexaaluminate powder with magnetoplumbite structure
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Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgy Mineral Resources,Wuhan University of Science and Technology,The State Key Laboratory of Refractories and Metallurgy,Wuhan University of Science and Technology,,Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgy Mineral Resources,Wuhan University of Science and Technology

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    摘要:

    采用反向化学共沉淀-高温煅烧法制备了镁基六铝酸镧(LaMgAl11O19)粉体。利用X射线衍射、场发射扫描电子显微镜、高温原位X射线衍射及Rietveld晶体结构精修法对粉体的物相组成、显微形貌、晶体结构及晶格热膨胀行为进行了研究。结果表明,反向化学共沉淀制备的氢氧化物前驱体经1600 ℃热处理后完全转变为磁铅石结构的LaMgAl11O19,呈规则六方板片状,晶面光滑平整。采用高温原位XRD技术及Rietveld晶体结构精修系统研究了镁基六铝酸镧材料的晶格热膨胀行为。随着温度的升高,镁基六铝酸镧(LaMgAl11O19)晶格热膨胀表现出各向异性,晶胞参数a和c随温度变化关系为:aT=5.5821+1.625×10-5T+1.757×10-8T2+4.24×10-12T3,cT=21.9189+1.1952×10-4T+4.587×10-8T2+5.463×10-11T3。室温~1300 ℃,//a平均热膨胀系数为8.42×10-6/℃,//c平均热膨胀系数为12.54×10-6/℃。La-O键各向异性热膨胀是LaMgAl11O19晶格热膨胀各向异性的主要原因。

    Abstract:

    The lanthanum magnesium hexaaluminate (LaMgAl11O19) powder was prepared via reverse chemical coprecipitation and high-temperature calcination method. The phase composition, microstructure, crystal structure and anisotropic lattice thermal expansion were ananlyzed using X-ray diffractometer (XRD), field emission scanning electron microscope (FSEM), in-situ high temperature X-ray diffraction (HD-XRD) and Rietveld refnement. The results showed that the precursors were final transformed to LaMgAl11O19 at sintering temperature of 1600 oC, in which the hexagonal plane was regular and smooth. Anisotropic lattice thermal expansion of LaMgAl11O19 was investigated by HD-XRD using rietveld refnement method. The influence of temperature-related parameter on cell parameters was analyzed, of which aT=5.5821+1.625×10-5T+1.757×10-8T2+4.24×10-12T3 and cT=21.9189+1.1952×10-4T+4.587×10-8T2+5.463×10-11T3. Lattice thermal expansion of LaMgAl11O19 presented anisotropic characteristics. At ambient temperature to 1300 ℃, average coefficient of thermal expansion of LMA were obtained with TECs(//a)= 8.42×10-6 /℃, TECs(//c)=12.54×10-6 /℃. The variation of lattice thermall expansion of LaMgAl11O19 mainly due to the changes of La-O bond caused by temperatute.

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吴红丹,张锦化,雷新荣,周志辉.磁铅石结构LaMgAl11O19粉体制备及其晶格热膨胀[J].稀有金属材料与工程,2018,47(S1):59~62.[Hongdan Wu, Jinhua Zhang, Xinrong Lei, Zhihui Zhou. Preparation and lattice thermal expansion of lanthanum magnesium hexaaluminate powder with magnetoplumbite structure[J]. Rare Metal Materials and Engineering,2018,47(S1):59~62.]
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  • 收稿日期:2017-05-26
  • 最后修改日期:2018-02-06
  • 录用日期:2018-02-07
  • 在线发布日期: 2018-10-22
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