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BaZrxTi1-xO3陶瓷的制备及性能研究
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东北大学秦皇岛分校,东北大学秦皇岛分校,东北大学秦皇岛分校,东北大学,东北大学

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国家自然科学基金资助(项目号51474061)


Preparation and properties of BaZrxTi1-xO3 ceramics
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School of Resources and Materials,Northeastern University at QinHuangDao Branch,Northeastern University,School of Resources and Materials,Northeastern University at QinHuangDao Branch,Northeastern University,School of Resources and Materials,Northeastern University at QinHuangDao Branch,Northeastern University,School of materials science and Engineering,Northeastern University,School of materials science and Engineering,Northeastern University

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    摘要:

    采用固相法制备BaZrxTi1-xO3陶瓷,并研究Zr掺杂对BaTiO3陶瓷显微结构、相组成、介电和铁电性能的影响。研究表明,在现有的掺杂水平下,所得陶瓷均为单一钙钛矿结构,未出现杂相。SEM分析表明,随Zr含量的增加,材料的晶粒尺寸显著长大,说明Zr对晶粒长大有促进作用。Zr含量对陶瓷的介电常数有明显的影响,当x = 0.15时,εr最大,例如在频率为3MHz时,εr达到4900左右。铁电性研究表明,随Zr含量的增加,存在漏电流增大的趋势,使得铁电性恶化。除x = 0.15的样品外,其余组分样品的剩余极化强度均随着Zr含量的增加而呈下降趋势,而矫顽场则随Zr含量的增加而增大。

    Abstract:

    A series of BaZrxTi1-xO3(x = 0.05, 0.1, 0.15, 0.2) ceramics were prepared by solid-state reaction. The effect of Zr content in BaTiO3 system on the structure, phase composition, dielectric and ferroelectric properties had been investigated. The results showed that all samples were found to crystallize in the perovskite single phase, without any second phase. The SEM pictures showed that the grain size increased obviously with the increasing of Zr content, which acted as a grain growth promotor. The dielectric constants were affected by the doping level of Zr, and increased to the maximum of 4900 for the sample of x = 0.15 at 3 MHz. In addition to the sample of x = 0.15, the remnant polarization of other ceramics was decreased with the increase of Zr content, while the coercive field increased. There was the tendency of increase the leakage current with the increase of Zr, which leaded to the deterioration of the ferroelectric properties.

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张晓燕,齐西伟,范明月,张敏,李颖. BaZrxTi1-xO3陶瓷的制备及性能研究[J].稀有金属材料与工程,2018,47(S1):63~66.[Zhang Xiaoyan, Qi Xiwei, Fan Mingyue, Zhang Min, Li Ying. Preparation and properties of BaZrxTi1-xO3 ceramics[J]. Rare Metal Materials and Engineering,2018,47(S1):63~66.]
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  • 收稿日期:2017-05-29
  • 最后修改日期:2018-02-24
  • 录用日期:2018-02-26
  • 在线发布日期: 2018-10-22
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