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烧结温度对铁尾矿多孔陶瓷结构及性能的影响
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北京交通大学 机械与电子控制工程学院,北京交通大学 机械与电子控制工程学院,北京交通大学 机械与电子控制工程学院,北京交通大学 机械与电子控制工程学院,北京交通大学 机械与电子控制工程学院,北京交通大学 机械与电子控制工程学院

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TM285

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国家自然科学基金资助(项目号M14A300020)


Effect of Sintering Temperature on Structure and Properties of Tailing Porous Ceramics
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School of Mechanical and Electronic Control Engineering,Beijing Jiaotong University,School of Mechanical and Electronic Control Engineering,Beijing Jiaotong University,School of Mechanical and Electronic Control Engineering,Beijing Jiaotong University,School of Mechanical and Electronic Control Engineering,Beijing Jiaotong University,School of Mechanical and Electronic Control Engineering,Beijing Jiaotong University,School of Mechanical and Electronic Control Engineering,Beijing Jiaotong University

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    摘要:

    本文以北京密云地区铁尾矿为原料,采用水基料浆泡沫注凝成形-无压烧结工艺制备了具有高气孔率的铁尾矿多孔陶瓷。结合X射线衍射(XRD)分析、扫描电镜(SEM)观察及性能测试结果,探讨了烧结温度对铁尾矿多孔陶瓷的孔隙率、体积密度、物相组成、抗压强度、显微结构和孔径分布的影响规律。结果表明:采用泡沫注凝法制备的铁尾矿多孔陶瓷的气孔结构复杂,由大的球形气孔与分布于球形孔壁上的微气孔组成,球形孔径均匀分布于20~70 μm之间。随着烧结温度从1070 °C升高到1120 °C,多孔陶瓷的显气孔率由89%降低至72%,体积密度由0.29 g/cm3上升至0.76 g/cm3,抗压强度由0.46 MPa上升至6.19 MPa。当温度升高至1120 °C时,尾矿中的主晶相石英因溶解于液相而使其衍射峰明显变弱,同时烧结体进一步收缩致密化,结构更加紧密,使得强度显著提高。

    Abstract:

    Tailing porous ceramics that iron tailings as the raw material were prepared by foam-gelcasting method and pressureless sintering process. The effect of sintering temperature on prosity, bulk density, compressive strength, Phase composition, microstructure and pore size distribution. Results show that as sintering temperature increased, porosity declined to 72% from 89%, the volume density and coirpressive strength increased to 0.76 g/cm3 and 6.19MPa respectively. When the sintering temperature is 1100°C, the diffraction peak of Quartz become wider and weak. It means that quartz is melting in liquid phase to increase the density and mechanical properties of tailing porous ceramics. The pore size is uniformly distributed in the 20μm to 70μm as the sintering temperature increases.

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李润丰,周 洋,郑 涌,孙智勇,李翠伟,黄振莺.烧结温度对铁尾矿多孔陶瓷结构及性能的影响[J].稀有金属材料与工程,2018,47(S1):103~107.[Li Runfeng, Zhou Yang, Zheng Yong, Sun Zhiyong, Li Cuiwei, Huang Zhenying. Effect of Sintering Temperature on Structure and Properties of Tailing Porous Ceramics[J]. Rare Metal Materials and Engineering,2018,47(S1):103~107.]
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  • 收稿日期:2017-06-02
  • 最后修改日期:2018-02-01
  • 录用日期:2018-02-05
  • 在线发布日期: 2018-10-22
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