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碳化钨对放电等离子烧结氮化硅陶瓷的致密化及力学性能的影响
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清华大学新型陶瓷与精细工艺国家重点实验室,辽宁科技大学,辽宁科技大学,清华大学新型陶瓷与精细工艺国家重点实验室

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Effect of Tungsten Carbide on Densification and Mechanical Properties of Silicon Nitride Ceramics by Spark Plasma Sintering
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State Key Laboratory of New Ceramics and Fine Processing,Tsinghua University,Liaoning High Temperature Materials and Magnesium Resource Engineering College,University of Science and Technology,Liaoning High Temperature Materials and Magnesium Resource Engineering College,University of Science and Technology,State Key Laboratory of New Ceramics and Fine Processing,Tsinghua University

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    摘要:

    以Al2O3-Y2O3烧结助剂,采用特制的碳化钨球磨罐与球磨子,通过机械球磨的方法向氮化硅陶瓷中引入碳化钨(WC),采用放电等离子烧结技术(SPS)进行快速烧结,制备出高性能β相氮化硅陶瓷。分析了碳化钨对氮化硅陶瓷致密化及力学性能的影响,结果表明:碳化钨的引入有效地降低了β相沉淀析出并继续生长的激活能,促进了氮化硅陶瓷α相→β相转变,实现烧结试样的致密化;随着碳化钨引入量的增加,烧结试样的抗弯强度从729 MPa急剧增加至1 090 MPa,提高了49.5%。

    Abstract:

    The high-performance silicon nitride ceramics were prepared by spark plasma sintering (SPS) with Al2O3–Y2O3 as a sintering aid.A novel approch was adopted to fabricate the silicon nitride by introducting WC via mechanical ball milling.The effects of tungsten carbide on densification and mechanical properties of silicon nitride ceramics were inverstigated.The results show that the introduction of tungsten carbide effectively reduces the activation energy of β phase precipitation and growth, which promotes the phase transformation of silicon nitride ceramic , and the densification of sintered samples. Tungsten carbide can dissolve into the matrix lattice partly.With the increase of the amount of tungsten carbide, the flexural strength of sintered samples increased from 735.2MPa to 1091.2MPa, which increased by 48.4%.

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刘剑,李志坚,罗旭东,谢志鹏.碳化钨对放电等离子烧结氮化硅陶瓷的致密化及力学性能的影响[J].稀有金属材料与工程,2018,47(S1):241~244.[Liu Jian, Li Zhijian, Luo Xudong, Xie Zhipeng. Effect of Tungsten Carbide on Densification and Mechanical Properties of Silicon Nitride Ceramics by Spark Plasma Sintering[J]. Rare Metal Materials and Engineering,2018,47(S1):241~244.]
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  • 收稿日期:2017-06-23
  • 最后修改日期:2018-03-01
  • 录用日期:2018-03-05
  • 在线发布日期: 2018-10-22
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