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MeO掺杂AgSnO2电接触材料的结构与性能
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1.浙江工业大学材料科学与工程学院;2.浙江大学浙江加州国际纳米技术研究院

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浙江省重点研发计划项目(No. 2017C01051);浙江省自然科学基金(No. LQ17E010002)


Microstructure and Properties of MeO Doped Ag/SnO2 Electric Contact Materials
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1.College of Materials Science and Engineering,Zhejiang University of Technology;2.Zhejiang-California International Nanotechnology Institute,Zhejiang University

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    摘要:

    采用机械合金化技术将不同用量的CuO或Fe2O3粉掺入银和SnO2粉中制备Ag/SnO2(x)-MeO(y)复合粉体,并辅以热压成型工艺制得Ag/SnO2(x)-MeO(y)电接触材料。采用扫描电镜、X射线衍射仪、电阻测试仪、硬度计及拉伸试验机等测试仪器对材料的组织结构、物理和力学性能进行了表征。结果表明:随着掺杂剂用量的增加,Ag/SnO2(x)-MeO(y)材料的密度逐渐降低,且CuO较Fe2O3更利于提高材料的导电性。两种掺杂剂均能显著改善Ag/SnO2(x)-MeO(y)材料的塑性变形能力。Ag/SnO2(11.2%)-CuO(0.8%) (也即CuO用量为0.8%)材料的电阻率达到最低值2.35 μΩ.cm,延伸率约为9.1%,比Ag/SnO2材料的延伸率提高近93.6%,综合性能最优。

    Abstract:

    Ag/SnO2(x)-MeO(y) composite powders were obtained by means of mechanical alloying different contents of CuO or Fe2O3 powders with Ag and SnO2 powders, and Ag/SnO2(x)-MeO(y) electrical contact materials were prepared by hot pressing process. The microstructure and physical and mechanical properties of the materials were characterized by scanning electron microscopy, X-ray diffractometry, resistance tester, hardness tester and tensile tester. The results show that the density of Ag/SnO2(x)-MeO(y) materials decreases with the increase of dopant content, and CuO is more conducive to improving the conductivity of Ag/SnO2(x)-MeO(y) material than Fe2O3. The two dopants can obviously improve the capacity of plastic deformation of Ag/SnO2(x)-MeO(y) material. The Ag/SnO2(11.2%)-CuO(0.8%) material (i.e. CuO content =0.8%) exhibits the best comprehensive properties with the resistivity about 2.35 μΩ?cm, elongation about 9.1% (higher than that of Ag/SnO2 material by 93.6%).

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杨芳儿,王贵葱,穆成法,吴君臣,沈涛,张玲洁,郑晓华. MeO掺杂AgSnO2电接触材料的结构与性能[J].稀有金属材料与工程,2020,49(4):1301~1305.[Yang Fanger, Wang Guicong, Mu Chengfa, Wu Junchen, Shen Tao, Zhang Lingjie, Zheng Xiaohua. Microstructure and Properties of MeO Doped Ag/SnO2 Electric Contact Materials[J]. Rare Metal Materials and Engineering,2020,49(4):1301~1305.]
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  • 收稿日期:2019-05-12
  • 最后修改日期:2019-08-01
  • 录用日期:2019-10-14
  • 在线发布日期: 2020-05-07
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