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原位析出TiB2-Ti2AlN策略增强TiAl合金力学性能
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衢州学院浙江省空气动力装备技术重点实验室

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Enhancing the mechanical properties of TiAl alloys by the in-situ precipitation of hybrid TiB2–Ti2AlN strategy
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Key Laboratory of Air-driven Equipment Technology of Zhejiang Province,Quzhou University

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    摘要:

    采用放电等离子烧结技术对TiAl合金和BN纳米片混合粉末在1300 ℃进行烧结,原位合成了TiB2-Ti2AlN /TiAl复合材料。对TiAl复合材料的显微组织演变和室温力学性能进行了系统的研究。结果表明,添加低含量BN纳米片的TiAl复合材料为全片层组织,而添加高含量BN纳米片的TiAl复合材料向近片层组织转变。此外,在原位合成的TiB2-Ti2AlN颗粒均匀分布在片层团晶界处显著细化了复合材料组织。当添加BN纳米片含量为0.5 wt%时,TiB2-Ti2AlN颗粒在片层团晶界处形成连续核壳结构。室温压缩和摩擦磨损结果表明,随着BN纳米片含量从0增加到1 wt%,TiAl复合材料的显微硬度和抗压强度显著提高,摩擦磨损系数则从0.59降低到0.47,磨损率降低了29.9%。TiAl复合材料优异的力学性能主要归因于原位析出的TiB2-Ti2AlN颗粒、细化的显微组织和核壳结构所产生的强化效应。

    Abstract:

    To strengthening the mechanical properties of TiAl alloys, hybrid TiB2–Ti2AlN/TiAl composites with a core-shell structure were in-situ fabricated by addition BN nanoplates using spark plasma sintering. A thorough investigation was conducted on the microstructural evolution and mechanical properties of TiAl composites. Fully lamellar microstructure can be achieved at low content BN nanoplates, while a nearly lamellar microstructure was observed at high content. The microstructure of synthesized TiAl composites were significantly refined due to the in-situ precipitation of TiB2-Ti2AlN particles at the lamellar colony boundaries. Notably, a novel continuous core-shell structure was formed when the BN nanoplates content reached 0.5 wt%. In addition, the mechanical properties of these composites were found to be superior compared to those of pure TiAl alloys. With an increase in BN nanoplates content from 0 to 1 wt%, both the micro-hardness and compressive strength were improved. Meanwhile, the average coefficient of friction decreased from 0.59 to 0.47 at room temperature, and the wear rate exhibited a noteworthy decrease of 29.9%. These remarkable improvements in mechanical performance can be mainly attributed to the strengthening effects resulting from the in-situ formation of TiB2–Ti2AlN particles, refined microstructure, and the novel core-shell structure.

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王玉鹏,李思颖,马腾飞,王晓红,董多,朱冬冬.原位析出TiB2-Ti2AlN策略增强TiAl合金力学性能[J].稀有金属材料与工程,,().[Wang Yupeng, Li Siying, Ma Tengfei, Wang Xiaohong, Duo Dong, Zhu Dongdong. Enhancing the mechanical properties of TiAl alloys by the in-situ precipitation of hybrid TiB2–Ti2AlN strategy[J]. Rare Metal Materials and Engineering,,().]
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  • 收稿日期:2024-01-01
  • 最后修改日期:2024-03-20
  • 录用日期:2024-03-22
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