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High Temperature Oxidation Behavior of Pure Ti TIG Welded Joint
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1.National Key Laboratory of Oil and Gas Drilling and Transportation Equipment, Tubular Goods Research Institute of China National Petroleum Corporation, Xi'an 710077, China;2.School of Materials Science and Engineering, Xi'an Shiyou University, Xi'an 710065, China;3.State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China

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Program of Key Technologies on Evaluation and Repair of Casing Damaging in Oil and Gas Well (2021DJ2705)

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    Abstract:

    The oxidation behavior, oxidation morphology, and oxidation products of pure Ti joint welded by tungsten inert gas welding technique at 550 °C for different durations (2, 4, 6, and 8 h) and those at different temperatures (650, 750, 850, and 950 °C) for 4 h were investigated. Results show that at 550 °C, the oxidation time has a slight influence on the oxidation behavior of welded joint. The oxidation temperature has a significant impact on the oxidation behavior, and the higher the temperature, the more severe the oxidation of welded joints. The oxidation kinetics is very close to the quasi-linear law at low temperatures. With increasing the temperature, the oxidation rate is increased exponentially. Additionally, the oxidation products generated on the surface of welded joint are TiO2 with anatase and rutile structures, and the temperature barely has effect on the TiO2 type. The oxidation process of pure Ti welded joint can be described as follows: oxygen atoms are absorbed on the surface; oxides preferentially nucleate in the defective zone; oxides grow laterally and the oxidation film becomes thicker. At relatively higher temperatures, the cracks or voids appear in the oxidation film, which become the transmission channels of O atoms, leading to the high diffusion rate of O and Ti atoms and high oxidation rate.

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[Han Lihong, Yang Shangyu, Wang Jianjun, Luo Sheji, Li Dan, Liu Ming. High Temperature Oxidation Behavior of Pure Ti TIG Welded Joint[J]. Rare Metal Materials and Engineering,2024,53(2):350~356.]
DOI:10.12442/j. issn.1002-185X.20230291

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History
  • Received:May 15,2023
  • Revised:June 25,2023
  • Adopted:June 28,2023
  • Online: February 27,2024
  • Published: February 23,2024